SDBS-assisted hydrothermal synthesis of flower-like Ni–Mo–S catalysts and their enhanced hydrodeoxygenation activity†,10.1039/C5RA20086E

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SDBS-assisted hydrothermal synthesis of flower-like Ni–Mo–S catalysts and their enhanced hydrodeoxygenation activity†

Song Tan,Guohua Zhu,Kui Wu,Liang Tan,Yingze Li

RSC Advances Pub Date : 10/30/2015 00:00:00 , DOI:10.1039/C5RA20086E

Abstract

Ni–Mo–S catalysts were prepared by sodium dodecyl benzene sulfonate (SDBS) assisted hydrothermal synthesis. The presence of SDBS increased the NiS₂ crystallite size, enlarged the interlayer distance of MoS₂ plane and formed loose flower-like architecture, which contributed to the enhanced HDO activity. Compared with Ni–Mo–S synthesized in the absence of SDBS, p-cresol conversion, methylcyclohexane selectivity and deoxygenation degree was increased by 24%, 25.1% and 26.3%, respectively.