Exploring simple, efficient and low cost photocatalysts for hydrogen production driven by visible light is a hot topic in the field of photocatalysis. Here, we study a two-dimensional (2D) layered SiC/C₂N van der Waals heterostructure as a possible visible light photocatalyst for water splitting, using hybrid density functional theory calculations. We find that the heterostructure composed of SiC and C₂N is a type II heterostructure with a mild band gap (1.58 eV), which can promote the effective separation of electron–hole pairs, thereby suppressing the recombination of photogenerated carriers. The phonon dispersion and ab initio molecular dynamics analysis indicate its good kinetic and thermodynamic stability. Remarkably, atomic projection density of states and energy band structure show that the valence band maximum (VBM) and conduction band minimum (CBM) of the SiC/C₂N heterostructure are provided by SiC and C₂N, respectively. And its band edge meets the requirements of the redox potential for water splitting. In addition, as the SiC-based heterostructure can retain the excellent visible light performance of the C₂N component, it laid the foundation for designing visible-light-driven SiC/C₂N photocatalysts. This work may provide valuable information for experimenters to design type II heterostructure photocatalytic materials for water splitting.