Synthesis and UHV-STM observation of the Td-symmetric Lu metallofullerene: Lu2@C76(Td)†
Hisashi Umemoto,Kazunori Ohashi,Takashi Inoue,Nobuyuki Fukui,Toshiki Sugai,Hisanori Shinohara
Chemical Communications Pub Date : 06/21/2010 00:00:00 , DOI:10.1039/C0CC00824A
Abstract

The first Td-symmetric lutetium metallofullerene, Lu2@C76, has been synthesized, isolated, and characterized. Because of the charge transfer from the encapsulated Lu atoms to the Td-C76 fullerene cage, the otherwise unstable Td-C76 fullerene can be significantly stabilized as a Lu2@C76 fullerene. Both STM and STS results are consistent with a charge state of (Lu2)6+@C766−(Td).

Graphical abstract: Synthesis and UHV-STM observation of the Td-symmetric Lu metallofullerene: Lu2@C76(Td)