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Regio-selective and stereo-selective hydrosilylation of internal alkynes catalyzed by ruthenium complexes†
Chunpu Li,Jiang Wang
RSC Advances Pub Date : 08/07/2018 00:00:00 , DOI:10.1039/C8RA04083D
Abstract

In this study, ruthenium(II)-catalyzed direct hydrosilylation of internal alkynes with high regio-selectivity and stereo-selectivity is reported. This title transformation led to various vinylsilanes in good to excellent yields. This approach features mild reaction conditions, low catalyst loading, air-stability, and good functional group tolerance. Furthermore, gram-scale preparation and some transformations of vinylsilanes were carried out, which further underscored its synthetic utility and applicability.

Graphical abstract: Regio-selective and stereo-selective hydrosilylation of internal alkynes catalyzed by ruthenium complexes
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