Thermal and near-infrared light induced spin crossover in a mononuclear iron(ii) complex with a tetrathiafulvalene-fused dipyridophenazine ligand†,10.1039/C6DT00920D

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Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

Thermal and near-infrared light induced spin crossover in a mononuclear iron(ii) complex with a tetrathiafulvalene-fused dipyridophenazine ligand†

F. Pointillart,X. Liu,M. Kepenekian,B. Le Guennic,S. Golhen,V. Dorcet,T. Roisnel,O. Cador,Z. You,J. Hauser,S. Decurtins,L. Ouahab,S.-X. Liu

Dalton Transactions Pub Date : 06/24/2016 00:00:00 , DOI:10.1039/C6DT00920D

Abstract

A mononuclear Fe(II) complex involving a tetrathiafulvalene-based ligand exhibits thermal spin-crossover (around 143 K) with pronounced hysteresis behaviour (48 K). The chromophoric and π-extended ligand allows Near-Infrared (NIR) sensitization for the light-induced excited spin-state trapping (LIESST) with T(LIESST) = 90 K.