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Shape-conserving enhancement of vibrational circular dichroism in lanthanide complexes†
Samuele Lo Piano,Sebastiano Di Pietro,Lorenzo Di Bari
Chemical Communications Pub Date : 10/25/2012 00:00:00 , DOI:10.1039/C2CC36455G
Abstract

The VCD spectra of lanthanide chelates with two chiral ligands display conserved sequences of bands throughout the Ln series. Some compounds (Tm, Yb) feature increased bands and strongly improved signal-to-noise ratios, an effect we dub Lanthanide Induced VCD Enhancement (LIVE).

Graphical abstract: Shape-conserving enhancement of vibrational circular dichroism in lanthanide complexes
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