A series of novel BiPO₄–BiOBr_xI_1−x p–n heterojunctions were successfully prepared by a facile solvothermal method. The morphology, structure and optical properties of photocatalysts were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) and ultraviolet visible diffuse reflectance spectroscopy. The visible light photocatalytic activities of BiPO₄–BiOBr_xI_1−x heterojunctions were investigated by photocatalytically reducing CO₂. After 4 hours of irradiation, the 5% BiPO₄–BiOBr_0.75I_0.25 heterojunction showed the highest photocatalytic activity with the yields of CO and CH₄ up to 24.9 and 9.4 μmol g_cat⁻¹ respectively. The improved photocatalytic activity may be due to the formation of BiPO₄–BiOBr_xI_1−x p–n heterojunctions which can effectively restrict the recombination rate of the photoexcited charge carriers. Moreover, the energy band structure of BiPO₄–BiOBr_xI_1−x heterojunctions could be easily adjusted by changing the mole ratio of I and Br. The possible mechanism of the enhancement of the photocatalytic performance was also proposed based on experimental and theoretical analysis. The present study may provide a rational strategy to design highly efficient heterojunctions with an adjustable energy band for environmental treatment and energy conversion.