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Acceptor directionality of sterically unhindered C–H⋯OC hydrogen bonds donated by acidic C–H groups
Chemical Communications Pub Date : 01/01/1900 00:00:00 , DOI:10.1039/CC9960001277
Abstract

Crystal correlation study of acidic and sterically unhindered C–H groups (chloroform, dichloromethane and terminal alkynes) forming short contacts with carbonyl acceptors, reveals a soft but significant preference for the conventional carbonyl lone-pair direction.

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