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Unprecedented preparation of pincer bis(oxazolinyl)phenyl ligands on solid support and their use in the first heterogeneously-catalyzed enantioselective allylation of aldehydes†
Avi Weissberg,Moshe Portnoy
Chemical Communications Pub Date : 05/29/2003 00:00:00 , DOI:10.1039/B301308A
Abstract

Unprecedented solid-phase synthesis of bis(oxazolinyl)phenyl (Phebox) ligands via an efficient five-step sequence led to the demonstration of the first heterogeneously-catalysed enantioselective allylation of aldehydes.

Graphical abstract: Unprecedented preparation of pincer bis(oxazolinyl)phenyl ligands on solid support and their use in the first heterogeneously-catalyzed enantioselective allylation of aldehydes
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