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The synthesis of a di-N-heterocyclic carbene-amido complex of palladium(ii)†
Richard E. Douthwaite,Jennifer Houghton,Benson M. Kariuki
Chemical Communications Pub Date : 02/13/2004 00:00:00 , DOI:10.1039/B314814A
Abstract

A diimidazolium salt incorporating a secondary amine moiety has been used to prepare a palladium(II) di-N-heterocyclic carbene amino complex that can be deprotonated with NaH to give the first example of a transition metal NHC–amide.

Graphical abstract: The synthesis of a di-N-heterocyclic carbene-amido complex of palladium(ii)
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