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An efficient and inexpensive water-oxidizing manganese-based oxide electrode†
Seyedeh Maedeh Hosseini
Dalton Transactions Pub Date : 09/16/2016 00:00:00 , DOI:10.1039/C6DT02292H
Abstract

Using inexpensive and environmentally friendly Mn oxide, a very simple method to synthesize an efficient and stable water-oxidizing electrode on the surface of a fluorine doped tin oxide electrode was reported. The electrode at pH = 13 yields a current density of 1 mA cm−2 at an overpotential of 450 mV, which is promising to be used as an anode in water-splitting systems. In higher overpotential (800 mV), a current density of 7 mA cm−2 was observed. Proposed different states of the growth of layered Mn oxide on the surface of FTO based on SEM images were also discussed.

Graphical abstract: An efficient and inexpensive water-oxidizing manganese-based oxide electrode
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