Solvothermal and mechanochemical intercalation of Cu into La2O2S2 enabled by the redox reactivity of (S2)2− pairs†,10.1039/D1DT01976G

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Lactoyl-CoA 全氟丁基戊烷白叶藤碱全氟己基辛烷新白叶藤碱壳寡糖特色专题-生物多肽

Solvothermal and mechanochemical intercalation of Cu into La2O2S2 enabled by the redox reactivity of (S2)2− pairs†

Shunsuke Sasaki,Gwladys Steciuk,Catherine Guillot-Deudon,Maria Teresa Caldes,Isabelle Braems,Etienne Janod,Benoît Corraze,Stéphane Jobic,Laurent Cario

Dalton Transactions Pub Date : 08/07/2021 00:00:00 , DOI:10.1039/D1DT01976G

Abstract

Intercalation of Cu into layered polychalcogenide La₂O₂S₂ was demonstrated to be viable both under solvothermal conditions at 200 °C and mechanical ball milling at ambient temperature. This result evidences the soft-chemical nature of metal intercalation into layered polychalcogenides driven by the redox reactivity of anion–anion bonds.