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Synthesis and properties of a trapezoid shaped macrocycle with different [n]yne units†
Maude Desroches,Jean-François Morin
RSC Advances Pub Date : 03/17/2017 00:00:00 , DOI:10.1039/C7RA01721A
Abstract

A new alkyne-based macrocycle that combines monoyne, diyne and tetrayne is reported. Despite its unusual trapezoid shape, the bending of the tetrayne unit allows the macrocycle to be unstrained. The macrocycle is synthesized by a combination of selective deprotection of silylated alkyne, Castro–Stephen–Sonogashira coupling and copper-mediated oxidative homocoupling. The final intramolecular cyclization proceeded in surprisingly high yield (72%) using modified Eglinton conditions in moderate dilution.

Graphical abstract: Synthesis and properties of a trapezoid shaped macrocycle with different [n]yne units
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