An ultra-incompressible ternary transition metal carbide
Shuailing Ma,Kuo Bao,Qiang Tao,Xiaoli Huang,Pinwen Zhu,Tian Cui
RSC Advances Pub Date : 11/07/2014 00:00:00 , DOI:10.1039/C4RA13193B
Abstract

The ternary transition metal carbide Mo0.5W0.5C was synthesized under high pressure and high temperature and the crystalline structure was confirmed by Rietveld refinements as being hexagonal (P[6 with combining macron]m2). The mechanical properties, bulk modulus and Vickers hardness were also investigated by in situ high-pressure X-ray diffraction and Vickers microhardness testing, respectively. The fitting bulk modulus of the ternary transition metal carbide is 399.9 ± 9.3 GPa, which is as compressible as diamond, and its asymptotic Vickers hardness is 15.3 GPa, nearly 60% harder than molybdenum carbide. The high bulk modulus is attributed to the high valence electron density and the greater hardness compared with γ-MoC is due to the strong bond between tungsten and carbon atoms.

Graphical abstract: An ultra-incompressible ternary transition metal carbide