Carbon nanomaterials have attracted widespread attention in electrochemical energy conversion due to their large surface area, excellent electrical/thermal conductivity and good chemical stability. However, the structure–activity relationship of carbon nanomaterials remains unclear. This review is thus on the synthesis methods of carbon nanomaterials including two-dimensional graphene, graphene nanoribbons, nanographene, heteroatom doped porous carbon and graphdiyne as electrocatalysts for the hydrogen evolution reaction, oxygen evolution reaction, and oxygen reduction reaction in fuel cells, electrolyzers and CO₂ reduction. The correlation between the electronic/chemical properties and electrochemical performance of synthetic carbon nanostructures will be profoundly discussed. Additionally, the emerging challenges and some perspectives on the development of synthetic carbon nanomaterials for electrochemical energy conversion are discussed.