Photoinduced nickel-catalyzed cross-coupling of arylsulfinates (ArSO₂⁻) with (hetero)aryl halides (Ar′–X) via visible light photoexcitation of 2-chloro-thioxanthen-9-one (Cl-TXO) has been achieved in moderate to excellent yields. This photocoupling exhibited a broad substrate scope with good functional group tolerance to give diarylsulfones. The mechanism involves oxidative addition of Ar′–X to Ni(0), oxidation with derived from single-electron-oxidation of ArSO₂⁻ by photoexcited Cl-TXO*, reductive elimination and release of the product diaryl sulfone and Ni^I catalyst. The photoredox and nickel catalytic cycles interact through electron transfer from the single-electron-reduced Cl-TXO ([Cl-TXO]˙⁻) to the Ni^I species.