Some unusual bridged sulphido-derivatives of iron carbonyl
Journal of the Chemical Society D: Chemical Communications Pub Date : , DOI:10.1039/C29700000288
Abstract
The reactions of Fe3(CO)12 with the secondary and tertiary alkyl thiols RSH (R = Pri, Bus, and But) in refluxing benzene afford the novel bridged sulphido-derivatives Fe3(CO)9(H)(SR), Fe3(CO)9(SBut)2, and Fe4(CO)12(SBut)2(S).
