The crystal structure of Me3SnNCS consists of zig-zag –S ⋯ Sn–NCS ⋯ Sn– chains, bent only at sulphur, with nearly planar trimethyltin groups.
![[double bond, length half m-dash]](http://hg.y866.cn/compound/lib/scimg/usr/1/C29690001125.jpg)
CS ⋯ Sn– chains, bent only at sulphur, with nearly planar trimethyltin groups.
