1172-76-5 (1,2-二甲基-1,1,2,2-四苯基二硅烷,Methyl-methyl(diphenyl)silyl-diphenylsilane)

CAS号:
1172-76-5
中文名称:
1,2-二甲基-1,1,2,2-四苯基二硅烷
英文名称:
Methyl-methyl(diphenyl)silyl-diphenylsilane
分子式:
C26H26Si2
分子量:
394.655648708344

1,2-二甲基-1,1,2,2-四苯基二硅烷(1172-76-5)名称与标识符

名称

中文别名:
1,2-二甲基-1,1,2,2-四苯基二硅烷;1,2-二甲基-1,1,2,2-四苯基乙硅烷;
英文别名:
Disilane,1,2-dimethyl-1,1,2,2-tetraphenyl-;1,2-Dimethyl-1,1,2,2-tetraphenyldisilane;methyl-[methyl(diphenyl)silyl]-diphenylsilane;TETRAPHENYLDIMETHYLDISILANE;1,1,2,2-tetraphenyl-1,2-dimethyldisilane;1,1-dimethyl-1,1,2,2-tetraphenyldisilane;1,2-dimethyltetraphenyldisilane;Disilane,1,2-dimethyl-1,1,2,2-tetraphenyl;Ph2MeSi-SiMePh2;1,2-dimethyl-1,1,2,2-tetraphenyl-disilan;Disilane, 1,2-dimethyl-1,1,2,2-tetraphenyl-;JNZRJYXUMDPPRK-UHFFFAOYSA-N;BC231157;D5031;1,2-dimeth-yl-1,1,2,2-tetraphenyldisilane;Q63409113;CS-0134271;AS-65805;3D95DQN4VJ;DTXSID1061578;C26H26Si2;FT-0606421;NS00044752;1172-76-5;UNII-3D95DQN4VJ;J-003548;D90358;EINECS 214-632-1;1,2-Dimethyl-1,1,2,2-tetraphenyldisilane, 97%;MFCD00051536;AKOS015913273;S07600;DTXCID5033414;

标识符

MDL:
MFCD00051536
InChIKey:
JNZRJYXUMDPPRK-UHFFFAOYSA-N
Inchi:
1S/C26H26Si2/c1-27(23-15-7-3-8-16-23,24-17-9-4-10-18-24)28(2,25-19-11-5-12-20-25)26-21-13-6-14-22-26/h3-22H,1-2H3
SMILES:
[Si](C)(C1C=CC=CC=1)(C1C=CC=CC=1)[Si](C)(C1C=CC=CC=1)C1C=CC=CC=1

1,2-二甲基-1,1,2,2-四苯基二硅烷(1172-76-5)物化性质

实验特性

  • LogP : 3.85080
  • PSA : 0.00000
  • 沸点 : 185°C/1mmHg(lit.)
  • 熔点 : 142.0 to 146.0 deg-C
  • 蒸气压 : 0.0±1.1 mmHg at 25°C
  • 闪点 : 207.3±14.3 °C
  • 颜色与性状 : 白色结晶性粉末
  • 溶解性 : 微溶于水
  • 最大波长(λmax) : 239(Cyclohexane)(lit.)
  • 密度 : 1.1±0.1 g/cm3

计算特性

  • 精确分子量 : 394.15700
  • 氢键供体数量 : 0
  • 氢键受体数量 : 0
  • 可旋转化学键数量 : 5
  • 同位素质量 : 394.15730390g/mol
  • 重原子数量 : 28
  • 复杂度 : 383
  • 同位素原子数量 : 0
  • 确定原子立构中心数量 : 0
  • 不确定原子立构中心数量 : 0
  • 确定化学键立构中心数量 : 0
  • 不确定化学键立构中心数量 : 0
  • 共价键单元数量 : 1
  • 疏水参数计算参考值(XlogP) : 无
  • 互变异构体数量 : 无
  • 表面电荷 : 0
  • 拓扑分子极性表面积 : 0

1,2-二甲基-1,1,2,2-四苯基二硅烷(1172-76-5)国际标准相关数据

EINECS:
214-632-1

1,2-二甲基-1,1,2,2-四苯基二硅烷(1172-76-5)海关数据

海关编码:
2931900090
海关数据:

中国海关编码:

2931900090

概述:

2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0%

Summary:

2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

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1,2-二甲基-1,1,2,2-四苯基二硅烷(1172-76-5)相关文献

1,2-二甲基-1,1,2,2-四苯基二硅烷(1172-76-5)参考资料

Reaxys RN:
2949874
PubChem CID:

1,2-二甲基-1,1,2,2-四苯基二硅烷(1172-76-5) MSDS

基础信息

Name:Tetraphenyldimethyldisilane Material Safety Data Sheet
Synonym:None Known
CAS:1172-76-5
Section 1 - Chemical Product ? MSDS Name:Tetraphenyldimethyldisilane Material Safety Data Sheet
Synonym:None Known

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS#Chemical NamecontentEINECS#
1172-76-5Tetraphenyldimethyldisilaneca. 100214-632-1
Hazard Symbols: XN
Risk Phrases: 20/21/22

Section 3 - HAZARDS IDENTIFICATION
? EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. May be harmful if inhaled.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
? Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
? General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam. Use agent most appropriate to extinguish fire.

Section 6 - ACCIDENTAL RELEASE MEASURES
? General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
? Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing.
Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
? Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 1172-76-5: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
?
Physical State: Crystals
Color: colorless - after melting, dark brown
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 138-140 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Negligible.
Specific Gravity/Density:
Molecular Formula: C26H26Si2
Molecular Weight: 394.353

Section 10 - STABILITY AND REACTIVITY
? Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
? RTECS#:
CAS# 1172-76-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Tetraphenyldimethyldisilane - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
?

Section 13 - DISPOSAL CONSIDERATIONS
? Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
?
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION
?
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
Safety Phrases:
S 36/37 Wear suitable protective clothing and
gloves.
WGK (Water Danger/Protection)
CAS# 1172-76-5: No information available.
Canada
CAS# 1172-76-5 is listed on Canada's NDSL List.
CAS# 1172-76-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1172-76-5 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A