1519-47-7 (对二亚甲苯双(氯化三苯基膦),(1,4-Phenylenebis(methylene))bis-(triphenylphosphonium) chloride)

CAS号:
1519-47-7
中文名称:
对二亚甲苯双(氯化三苯基膦)
英文名称:
(1,4-Phenylenebis(methylene))bis-(triphenylphosphonium) chloride
安全信息:
分子式:
C44H38Cl2P2
分子量:
699.626051425934

对二亚甲苯双(氯化三苯基膦)(1519-47-7)名称与标识符

名称

中文别名:
对二亚甲苯双(氯化三苯基膦);(1,4-亚苯基双(亚甲基))双-(三苯基磷) 氯化物;5-氟吡啶-2-甲酸乙酯;对二亚甲苯双(氯化三苯基鏻);对亚二甲苯双(氯化三苯基膦);对二亚甲苯双(氯化三苯基膦),95%;对二亚甲苯双(氯化三苯基鏻) 25G;对二亚甲苯双(氯化三苯基膦), 97+%;
英文别名:
(1,4-Phenylenebis(methylene))bis(triphenylphosphonium) chloride;P-Xylylenebis(triphenylphosphonium chloride);(1,4-Phenylenebis(methylene))bis-(triphenylphosphonium) chloride;bis(triphenylphosphonium);(1,4-Phenylenebis(methylene);1,4-bis(triphenylphosphoniomethyl)benzene dichloride;1,4-BIS(TRIPHENYLPHOSPHONIUMMETHYL)BENZENE DICHLORIDE;p-Xylylenebis(triphenylphospho;p-xylylenebis(triphenyl-phosphoniudichloride;p-Xylylenebis(triphenylphosphoniumchloride),99%;p-Xylylenebis(triphenylphosphonium chloride), 97+%;p-Xylylenebis(triphenylphosphonium chloride), 96 %;Phosphonium, p-xylylenebis(triphenyl-, dichloride;Phosphonium, [1,4-phenylenebis(methylene)]bis[triphenyl-, dichloride;Phosphonium, (p-phenylenedimethylene)bis(triphenyl-, dichloride;(p-Phenylenebis(methylene))bis(triphenylphosphonium) dichloride;Phosphonium, (1,4-phenylenebis(methylene))bis(triphenyl-, dichloride;NSC660328;IUNJPQCPINLADS-;BAA51947;IUNJPQCPINLADS-UHFFFAOYSA-L;AKOS015900232;J-008868;Phosphonium, 1,1'-(1,4-phenylenebis(methylene))bis(1,1,1-triphenyl-, chloride (1:2);MFCD00031710;1,4-Bis(triphenylphosphonuimmethyl)benzene dichloride;Phosphonium,1,1'-[1,4-phenylenebis(methylene)]bis[1,1,1-triphenyl-, chloride (1:2);FT-0633630;CHEMBL3391910;BCP21884;DTXSID40926795;triphenyl-[[4-(triphenylphosphaniumylmethyl)phenyl]methyl]phosphonium;1519-47-7;Phosphonium, [1,4-phenylenebis(methylene)]bis[triphenyl-, chloride;SCHEMBL2446696;NSC 64113;SY109413;[1,4-Phenylenebis(methylene)]bis(triphenylphosphanium) dichloride;EINECS 216-184-2;AMY39386;130547-46-5;triphenyl-[[4-(triphenylphosphaniumylmethyl)phenyl]methyl]phosphanium;dichloride;J-524069;NS00044379;Phosphonium, 1,1'-[1,4-phenylenebis(methylene)]bis[1,1,1-triphenyl-, chloride (1:2);216-184-2;[p-phenylenebis(methylene)]bis[triphenylphosphonium] dichloride;

标识符

MDL:
MFCD00031710
InChIKey:
IUNJPQCPINLADS-UHFFFAOYSA-L
Inchi:
1S/C44H38P2.2ClH/c1-7-19-39(20-8-1)45(40-21-9-2-10-22-40,41-23-11-3-12-24-41)35-37-31-33-38(34-32-37)36-46(42-25-13-4-14-26-42,43-27-15-5-16-28-43)44-29-17-6-18-30-44;;/h1-34H,35-36H2;2*1H/q+2;;/p-2
SMILES:
[Cl-].[Cl-].[P+](C1C=CC=CC=1)(C1C=CC=CC=1)(C1C=CC=CC=1)CC1C=CC(=CC=1)C[P+](C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1
BRN:
3876684

对二亚甲苯双(氯化三苯基膦)(1519-47-7)物化性质

实验特性

  • LogP : 2.68280
  • PSA : 27.18000
  • 沸点 : °Cat760mmHg
  • 熔点 : >300°C
  • 闪点 : °C
  • 颜色与性状 : 白色固体。
  • 溶解性 : 溶于水。
  • 敏感性 : Hygroscopic
  • 密度 : g/cm3

计算特性

  • 精确分子量 : 698.18300
  • 氢键供体数量 : 0
  • 氢键受体数量 : 2
  • 可旋转化学键数量 : 10
  • 同位素质量 : 698.183
  • 重原子数量 : 48
  • 复杂度 : 689
  • 同位素原子数量 : 0
  • 确定原子立构中心数量 : 0
  • 不确定原子立构中心数量 : 0
  • 确定化学键立构中心数量 : 0
  • 不确定化学键立构中心数量 : 0
  • 共价键单元数量 : 3
  • 表面电荷 : 0
  • 拓扑分子极性表面积 : 0

对二亚甲苯双(氯化三苯基膦)(1519-47-7)安全信息

对二亚甲苯双(氯化三苯基膦)(1519-47-7)国际标准相关数据

EINECS:
64113

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对二亚甲苯双(氯化三苯基膦)(1519-47-7)参考资料

Beilstein:
3876684
PubChem CID:

对二亚甲苯双(氯化三苯基膦)(1519-47-7) MSDS

基础信息

Name:p-Xylylenebis(triphenylphosphoniumchloride) Material Safety Data Sheet
Synonym:
CAS:1519-47-7
Section 1 - Chemical Product ? MSDS Name:p-Xylylenebis(triphenylphosphoniumchloride) Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS#Chemical NamecontentEINECS#
1519-47-7p-Xylylenebis(triphenylphosphoniumchlo216-184-2
Hazard Symbols: XN
Risk Phrases: 20/21/22 36/37/38

Section 3 - HAZARDS IDENTIFICATION
? EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Irritating to eyes, respiratory system and skin.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation:
Harmful if inhaled. Causes respiratory tract irritation.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
? Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
? General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
? General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Avoid generating dusty conditions.

Section 7 - HANDLING and STORAGE
? Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
? Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 1519-47-7: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
?
Physical State: Solid
Color: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C44H38Cl2P2
Molecular Weight: 699.64

Section 10 - STABILITY AND REACTIVITY
? Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, oxides of phosphorus, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
? RTECS#:
CAS# 1519-47-7: TA3580000 LD50/LC50:
Not available.
Carcinogenicity:
p-Xylylenebis(triphenylphosphoniumchloride) - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION
? Other No information available.

Section 13 - DISPOSAL CONSIDERATIONS
? Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
?
IATA
Shipping Name: ORGANOPHOSPHORUS COMPOUND, SOLID, TOXIC, N.O.S.*
Hazard Class: 6.1
UN Number: 3278
Packing Group: III
IMO
Shipping Name: ORGANOPHOSPHORUS COMPOUND, TOXIC, N.O.S. , SOLID
Hazard Class: 6.1
UN Number: 3278
Packing Group: III
RID/ADR
Shipping Name: ORGANOPHOSPHORUS COMPOUND, TOXIC, N.O.S.
Hazard Class: 6.1
UN Number: 3278
Packing group: III

Section 15 - REGULATORY INFORMATION
?
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 1519-47-7: No information available.
Canada
CAS# 1519-47-7 is listed on Canada's NDSL List.
CAS# 1519-47-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1519-47-7 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A