1530-37-6 (4-甲基苯三苯基氯化磷,4-METHYLBENZYL TRIPHENYLPHOSPHONIUM CHLORIDE)

CAS号:
1530-37-6
中文名称:
4-甲基苯三苯基氯化磷
英文名称:
4-METHYLBENZYL TRIPHENYLPHOSPHONIUM CHLORIDE
分子式:
C26H24ClP
分子量:
402.895526885986

4-甲基苯三苯基氯化磷(1530-37-6)名称与标识符

名称

中文别名:
4-甲基苯三苯基氯化磷;(4-甲基苄基)三苯基氯化膦;4-甲基苯三苯基磷酸氯;4-甲基苄基三苯基氯化磷;(4-甲基苄基)三苯基氯化磷鎓;4-苄基三苯基氯化磷;三(三苯基膦)溴化铑(I);(4-甲基苄基)三苯基氯化膦, 98+%;(4-甲基苄基)三苯基氯化磷鎓, 98+%;
英文别名:
4-METHYLBENZYL TRIPHENYLPHOSPHONIUM CHLORIDE;(P-METHYLBENZYL)TRIPHENYLPHOSPHONIUM CHLORIDE;[(4-METHYLPHENYL)METHYL]-TRIPHENYLPHOSPHONIUM CHLORIDE;(4-Methylbenzyl)triphenylphosphonium chloride;(4-methylphenyl)methyl-triphenylphosphanium,chloride;((4-methylphenyl)methyl)triphenylphosphonium chloride;<(4-Methylphenyl)methyl>triphenylphosphoniumchlorid;triphenyl(4-methylbenzyl)phosphonium chloride;(p-Methylbenzyl)triphenylphosphoniumchloride (6CI,7CI);Phosphonium, (p-methylbenzyl)triphenyl-, chloride (8CI);Phosphonium, [(4-methylphenyl)methyl]triphenyl-, chloride (9CI);4-Methylbenzyltriphenylphosphonium chloride;4-Methylbenzyltriphenylphosphonium chloride,99%;4-Methylbenzyl triphenylphosphonium chloride, 98+%;1530-37-6;CHEMBL2041840;A809381;p-Methylbenzyltriphenylphosphonium chloride;DTXSID50934649;E78177;FT-0605021;(4-methylphenyl)methyl-triphenylphosphanium;chloride;SCHEMBL2452316;Phosphonium, ((4-methylphenyl)methyl)triphenyl-, chloride;(4-Methylbenzyl)triphenylphosphoniumchloride;CS-0198951;triphenyl(p-tolylmethyl)phosphonium chloride;[(4-Methylphenyl)methyl](triphenyl)phosphanium chloride;METHYLN-BOC-L-PROLINE-3-ENE;AKOS017345195;MFCD00031581;J-008974;DB-043174;[(4-methylphenyl)methyl]triphenylphosphanium chloride;FM173376;667-047-2;

标识符

MDL:
MFCD00031581
InChIKey:
AZHSDLYDKBEFLL-UHFFFAOYSA-M
Inchi:
1S/C26H24P.ClH/c1-22-17-19-23(20-18-22)21-27(24-11-5-2-6-12-24,25-13-7-3-8-14-25)26-15-9-4-10-16-26;/h2-20H,21H2,1H3;1H/q+1;/p-1
SMILES:
[Cl-].[P+](C1C=CC=CC=1)(C1C=CC=CC=1)(C1C=CC=CC=1)CC1C=CC(C)=CC=1

4-甲基苯三苯基氯化磷(1530-37-6)物化性质

实验特性

  • LogP : 2.49310
  • PSA : 13.59000
  • 沸点 : °Cat760mmHg
  • 熔点 : 262℃
  • 闪点 : °C
  • 颜色与性状 : 固体。
  • 溶解性 : 未确定
  • 密度 : g/cm3

计算特性

  • 精确分子量 : 402.13000
  • 氢键供体数量 : 0
  • 氢键受体数量 : 0
  • 可旋转化学键数量 : 5
  • 同位素质量 : 402.130415
  • 重原子数量 : 28
  • 复杂度 : 372
  • 同位素原子数量 : 0
  • 确定原子立构中心数量 : 0
  • 不确定原子立构中心数量 : 0
  • 确定化学键立构中心数量 : 0
  • 不确定化学键立构中心数量 : 0
  • 共价键单元数量 : 2
  • 疏水参数计算参考值(XlogP) : 无
  • 互变异构体数量 : 无
  • 表面电荷 : 0
  • 拓扑分子极性表面积 : 0

4-甲基苯三苯基氯化磷(1530-37-6)安全信息

4-甲基苯三苯基氯化磷(1530-37-6)海关数据

海关编码:
2931900090
海关数据:

中国海关编码:

2931900090

概述:

2931900090. 其他有机-无机化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:AB(入境货物通关单,出境货物通关单). 最惠国关税:6.5%. 普通关税:30.0%

Summary:

2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

4-甲基苯三苯基氯化磷(1530-37-6)相关文献

4-甲基苯三苯基氯化磷(1530-37-6) MSDS

基础信息

Name:4-Methylbenzyltriphenylphosphonium chloride 99% Material Safety Data Sheet
Synonym:[(4-Methylphenyl)methyl]-triphenylphosphonium chloride
CAS:1530-37-6
Section 1 - Chemical Product ? MSDS Name:4-Methylbenzyltriphenylphosphonium chloride 99% Material Safety Data Sheet
Synonym:[(4-Methylphenyl)methyl]-triphenylphosphonium chloride

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS#Chemical NamecontentEINECS#
1530-37-64-Methylbenzyltriphenylphosphonium chl99unlisted
Hazard Symbols: XI
Risk Phrases: 36/37/38

Section 3 - HAZARDS IDENTIFICATION
? EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation:
Causes respiratory tract irritation.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
? Eyes: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical aid.
Skin:
In case of contact, flush skin with plenty of water. Remove contaminated clothing and shoes. Get medical aid if irritation develops and persists. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
? General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Runoff from fire control or dilution water may cause pollution.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.

Section 6 - ACCIDENTAL RELEASE MEASURES
? General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
? Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed.
Use with adequate ventilation. Avoid breathing dust.
Storage:
Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from moisture.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
? Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels.
Exposure Limits CAS# 1530-37-6: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
?
Physical State: Crystalline powder
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 262-264 deg C
Autoignition Temperature: Not available.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C26H24ClP
Molecular Weight: 402.89

Section 10 - STABILITY AND REACTIVITY
? Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Dust generation, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, oxides of phosphorus, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
? RTECS#:
CAS# 1530-37-6 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
4-Methylbenzyltriphenylphosphonium chloride - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION
?

Section 13 - DISPOSAL CONSIDERATIONS
? Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION
?
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:

Section 15 - REGULATORY INFORMATION
?
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 1530-37-6: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 1530-37-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1530-37-6 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A