63134-33-8 (4-羟基-4'-苄氧基二苯砜,4-Benzyloxyphenyl 4-Hydroxyphenyl Sulfone)

CAS号:
63134-33-8
中文名称:
4-羟基-4'-苄氧基二苯砜
英文名称:
4-Benzyloxyphenyl 4-Hydroxyphenyl Sulfone
安全信息:
分子式:
C19H16O4S
分子量:
340.392944335938

4-羟基-4'-苄氧基二苯砜(63134-33-8)名称与标识符

名称

中文别名:
4-羟基-4'-苄氧基二苯砜;4-苄氧苯基-4'-羟基苯基砜;4-苯氧苯基-4'-羟基苯基砜;4-Benzyloxyphenyl 4-Hydroxyphenyl Sulfone 4-苯氧苯基-4'-羟基苯基砜;4-苯氧苯基-4 -羟基苯基砜;4-苄氧苯基-4-羟基苯基砜;4-苄氧基-4ˊ-羟基二苯砜;4-羟基-4’-苄氧基二苯砜;4-羟基-4''-苄氧基二苯砜;4-苄氧苯基-4’-羟基苯基砜;
英文别名:
4-((4-(Benzyloxy)phenyl)sulfonyl)phenol;4-Benzyloxyphenyl 4-Hydroxyphenyl Sulfone;4-(4-phenylmethoxyphenyl)sulfonylphenol;4-[(4-Benzyloxyphenyl)sulfonyl]phenol;4-Benzyloxy-4'-hydroxydiphenylsulfone;4-Benzyloxyphenyl-4'-hydroxyphenyl sulfone;4-Hydroxy-4'-benzyloxydiphenyl sulfone;BPS-BN;p-(p-Benzyloxyphenylsulfonyl)phenol;EINECS 263-920-3;B2858;A834233;Phenol, 4-[[4-(phenylmethoxy)phenyl]sulfonyl]-;AKOS001686321;4-Benzyloxy-4'-hydroxydiphenyl sulfone;4-HYDROXY-4'-BENZYLOXY DIPHENYLSULFONE;FT-0658483;UWPJWCBDMZHMTN-UHFFFAOYSA-*******-Benzyloxyphenyl)sulphonyl)phenol;EU-0083784;4-((4-benzyloxyphenyl)sulfonyl)phenol;SCHEMBL419556;4-[4-(BENZYLOXY)BENZENESULFONYL]PHENOL;NS00035326;C19H16O4S;CS-0206177;63134-33-8;Bisphenol S-monobenzyl ether;MFCD00185925;D88970;Phenol, 4-((4-(phenylmethoxy)phenyl)sulfonyl)-;Oprea1_645542;4-{[4-(benzyloxy)phenyl]sulfonyl}phenol;4-Benzyloxyphenyl 4-hydroxyphenylsulfone;4-(4-(benzyloxy)phenylsulfonyl)phenol;4-hydroxy-4'-benzyloxy-diphenylsulfone;STK036562;

标识符

MDL:
MFCD00185925
InChIKey:
UWPJWCBDMZHMTN-UHFFFAOYSA-N
Inchi:
1S/C19H16O4S/c20-16-6-10-18(11-7-16)24(21,22)19-12-8-17(9-13-19)23-14-15-4-2-1-3-5-15/h1-13,20H,14H2
SMILES:
S(C1C=CC(=CC=1)O)(C1C=CC(=CC=1)OCC1C=CC=CC=1)(=O)=O

4-羟基-4'-苄氧基二苯砜(63134-33-8)物化性质

实验特性

  • LogP : 4.88480
  • PSA : 71.98000
  • 折射率 : 1.63
  • 沸点 : 558.6 ℃ at 760 mmHg
  • 熔点 : 168.0 to 173.0 deg-C
  • 蒸气压 : 0.0±1.6 mmHg at 25°C
  • 闪点 : 291.6 ℃
  • 颜色与性状 : 白色至微白色结晶性粉末。
  • 溶解性 : 不溶于水,溶于甲醇、乙醇、醋酸乙酯和丙酮等有机溶剂,。
  • 密度 : 1.304

计算特性

  • 精确分子量 : 340.07700
  • 氢键供体数量 : 1
  • 氢键受体数量 : 4
  • 可旋转化学键数量 : 5
  • 同位素质量 : 340.077
  • 重原子数量 : 24
  • 复杂度 : 462
  • 同位素原子数量 : 0
  • 确定原子立构中心数量 : 0
  • 不确定原子立构中心数量 : 0
  • 确定化学键立构中心数量 : 0
  • 不确定化学键立构中心数量 : 0
  • 共价键单元数量 : 1
  • 疏水参数计算参考值(XlogP) : 无
  • 互变异构体数量 : 2
  • 表面电荷 : 0
  • 拓扑分子极性表面积 : 72A^2

4-羟基-4'-苄氧基二苯砜(63134-33-8)国际标准相关数据

EINECS:
263-920-3

4-羟基-4'-苄氧基二苯砜(63134-33-8)海关数据

海关编码:
2909500000
海关数据:

中国海关编码:

2909500000

概述:

2909500000. 醚酚、醚醇酚及其卤化、磺化、硝化或亚硝化衍生物. 增值税率:17.0%. 退税率:9.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%

申报要素:

品名, 成分含量, 用途

Summary:

2909500000 ether-phenols, ether-alcohol-phenols and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

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4-羟基-4'-苄氧基二苯砜(63134-33-8)上下游

4-羟基-4'-苄氧基二苯砜(63134-33-8)参考资料

Reaxys RN:
6815300
Beilstein:
B152808
PubChem CID:

4-羟基-4'-苄氧基二苯砜(63134-33-8) MSDS

基础信息

  4-Benzyloxyphenyl 4-Hydroxyphenyl Sulfone      Revision number: 1    
  SAFETY DATA SHEET

Section 1. BASE INFORMATION
  Product name:        4-Benzyloxyphenyl 4-Hydroxyphenyl Sulfone    

  Revision number:        1    

Section 2. HAZARDS IDENTIFICATION
  Classification of the GHS
  PHYSICAL HAZARDS        Not classified    
  HEALTH HAZARDS
    Category 4
  Acute toxicity (Oral)
  Acute toxicity (Dermal)        Category 4    
    Category 4
  Acute toxicity (Inhalation)
  Skin corrosion/irritation        Category 2    
    Category 2A
  Serious eye damage/eye irritation
  ENVIRONMENTAL HAZARDS        Not classified    
  GHS label elements
  Pictograms or hazard symbols
  Signal word        Warning    
  Hazard statement        Harmful by inhalation, in contact with skin and if swallowed    
    Causes skin irritation
    Causes serious eye irritation
  Precautionary statements
  [Prevention]        Avoid breathing.    
    Use only outdoors or in a well-ventilated area.
    Do not eat, drink or smoke when using this product.
    Wash hands thoroughly after handling.
    Wear protective gloves and eye/face protection.
    IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
  [Response]
    breathing. Call a POISON CENTER or doctor/physician if you feel unwell.
    IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
    Rinse mouth.
    IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
    if present and easy to do. Continue rinsing.
    If eye irritation persists: Get medical advice/attention.
    IF ON SKIN: Gently wash with plenty of soap and water.
    If skin irritation occurs: Get medical advice/attention.
    Wash contaminated clothing before reuse.
    Call a POISON CENTER or doctor/physician if you feel unwell.
  [Disposal]        Dispose of contents/container through a waste management company authorized by    
    the local government

Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
  Substance/mixture:        Substance    
  Component(s):        4-Benzyloxyphenyl 4-Hydroxyphenyl Sulfone    
  Percent:        >98.0%(LC)(T)    
  CAS Number:        63134-33-8    
  Chemical Formula:        C19H16O4S    

Section 4. FIRST AID MEASURES
    Remove victim to fresh air and keep at rest in a position comfortable for breathing.
  Inhalation:
    Call a POISON CENTER or doctor/physician if you feel unwell.
  Skin contact:        Remove/Take off immediately all contaminated clothing. Gently wash with plenty of    
    soap and water. If skin irritation or rash occurs: Get medical advice/attention.
  Eye contact:        Rinse cautiously with water for several minutes. Remove contact lenses, if present    
    and easy to do. Continue rinsing. If eye irritation persists: Get medical
    advice/attention.
  Ingestion:        Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth.    
  Protection of first-aiders:        A rescuer should wear personal protective equipment, such as rubber gloves and air-    
    tight goggles.

Section 5. FIRE-FIGHTING MEASURES
  Suitable extinguishing        Dry chemical, foam, water spray, carbon dioxide.    
  media:
  Specific hazards:        Take care as it may decompose upon combustion or in high temperatures to    
    generate poisonous fume.
  Specific methods:        Fire-extinguishing work is done from the windward and the suitable fire-extinguishing    
    method according to the surrounding situation is used. Uninvolved persons should
    evacuate to a safe place. In case of fire in the surroundings: Remove movable
    containers if safe to do so.
  Special protective        When extinguishing fire, be sure to wear personal protective equipment.    
  equipment for firefighters:

Section 6. ACCIDENTAL RELEASE MEASURES
    Use personal protective equipment. Keep people away from and upwind of spill/leak.
  Personal precautions,
  protective equipment and Entry to non-involved personnel should be controlled around the leakage area by
  emergency procedures: roping off, etc.
  Environmental precautions: Prevent product from entering drains.
  Methods and materials for Sweep dust to collect it into an airtight container, taking care not to disperse it.
  containment and cleaning Adhered or collected material should be promptly disposed of, in accordance with
  up: appropriate laws and regulations.

Section 7. HANDLING AND STORAGE
  Handling
  Technical measures:        Handling is performed in a well ventilated place. Wear suitable protective equipment.    
    Prevent dispersion of dust. Wash hands and face thoroughly after handling.
    Use a local exhaust if dust or aerosol will be generated.
  Advice on safe handling:        Avoid contact with skin, eyes and clothing.    
  Storage
  Storage conditions:        Keep container tightly closed. Store in a cool and dark place.    
    Store away from incompatible materials such as oxidizing agents.
  Packaging material:        Law is followed.    

Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
  Engineering controls:        Install a closed system or local exhaust as possible so that workers should not be    
    exposed directly. Also install safety shower and eye bath.
  Personal protective equipment

Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
  Respiratory protection: Dust respirator. Follow local and national regulations.
  Hand protection:        Protective gloves.    
  Eye protection:        Safety glasses. A face-shield, if the situation requires.    
  Skin and body protection: Protective clothing. Protective boots, if the situation requires.

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
  Physical state (20°C):        Solid    
  Form:        crystal - powder    
  Color:        White - Almost white    
  Odor:        No data available    
  pH: No data available
  Melting point/freezing point:170 °C
  Boiling Point/Range:        No data available    
  Flash Point:        No data available    
  Explosive limits
  Lower:        No data available    
  Upper:        No data available    
  Density:        No data available    
  Solubility:        Soluble in : Methanol    

Section 10. STABILITY AND REACTIVITY
  Stability:        Stable under proper conditions.    
  Reactivity:        No special reactivity has been reported.    
  Incompartible materials: oxidizing agents
  Hazardous Decomposition Carbon monoxide, Carbon dioxide, Sulphur oxides
  Products:

Section 11. TOXICOLOGICAL INFORMATION
  Acute Toxicity:        No data available    
  Skin corrosion/irritation: No data available
  Serious eye        No data available    
  damage/irritation:
  Germ cell mutagenicity: No data available
  Carcinogenicity:
  IARC =        No data available    
    No data available
  NTP =
  Reproductive toxicity:        No data available    

Section 12. ECOLOGICAL INFORMATION
  Ecotoxicity:
  Fish:        No data available    
  Crustacea:        No data available    
    No data available
  Algae:
  Persistence / degradability: No data available
    No data available
  Bioaccumulative
  potential(BCF):
  Mobillity in soil
  log Pow:        No data available    
  Soil adsorption (Koc):        No data available    
  Henry's Law        No data available    
  constant(PaM3/mol):

Section 13. DISPOSAL CONSIDERATIONS
    Recycle to process, if possible. Consult your local regional authorities. You may be able to dissolve or mix material
    with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system.
    Observe all federal, state and local regulations when disposing of the substance.

Section 14. TRANSPORT INFORMATION
  Hazards Class:        Does not correspond to the classification standard of the United Nations    
  UN-No:        Not Listed    

Section 15. REGULATORY INFORMATION
  Safe management ordinance of dangerous chemical product (State Council announces on January 26,
  2002): Safe use and production, the storage of a dangerous chemical, transport, loading and unloading were
    prescribed.


SECTION 16 - ADDITIONAL INFORMATION
N/A