7789-42-6 (溴化镉,dibromocadmium)

结构式:
CAS号:
7789-42-6
中文名称:
溴化镉
英文名称:
dibromocadmium
分子式:
Br2Cd
分子量:
272.21900177002
简介:
白色至微黄色结晶性粉末。无气味。在空气中风化。久置或见光渐变黄色。溶于水、丙酮和乙醇,微溶于乙醚。相对密度5.192。熔点566℃。沸点963℃。有毒。有致癌可能性。

溴化镉(7789-42-6)名称与标识符

名称

中文别名:
溴化镉;溴化镉,AR;溴化鎘;溴化镉, 超干, 99.999% (METALS BASIS);溴化镉, 无水;溴化镉,无水,98%;无水溴化镉;溴化镉, 无水, 99.999% (主成分含量);溴化镉(II);
英文别名:
Cadmium bromide;Cadmiumbromideanhydrouswhitepowder;Cadmium bromide hydrate;cadmium(2+),dibromide;Cadmium dibromide;Cadmiumbromide (8CI);dibromocadmium;Cadmium bromide (CdBr2);cadmiumbromide(cdbr2);Cadmium(II) bromide, anhydrous 98%;cadmiumbromidedimer;CdBr2;

标识符

MDL:
MFCD00015996
InChIKey:
KPWJBEFBFLRCLH-UHFFFAOYSA-L
Inchi:
1S/2BrH.Cd/h2*1H;/q;;+2/p-2
SMILES:
[Cd+2].[Br-].[Br-]

溴化镉(7789-42-6)物化性质

实验特性

  • LogP : -5.99450
  • PSA : 0.00000
  • Merck : 14,1615
  • 水溶性 : Freely soluble in water, alcohol. Slightly soluble in acetone and ether.
  • 沸点 : 863°C
  • 熔点 : 567°C
  • 闪点 : 863°C
  • 溶解度 : Soluble in alcohol, ether, acetone and liquid ammonia.
  • 颜色与性状 : 无色结晶或白色结晶颗粒,久置或风化逐渐变黄。在干燥空气中风化。
  • 稳定性 : Stable.
  • 溶解性 : Freely soluble in water, alcohol. Slightly soluble in acetone and ether.
  • 敏感性 : Hygroscopic
  • 密度 : 5,192 g/cm3

计算特性

  • 精确分子量 : 271.74000
  • 氢键供体数量 : 0
  • 氢键受体数量 : 0
  • 可旋转化学键数量 : 0
  • 同位素质量 : 271.740033
  • 重原子数量 : 3
  • 复杂度 : 0
  • 同位素原子数量 : 0
  • 确定原子立构中心数量 : 0
  • 不确定原子立构中心数量 : 0
  • 确定化学键立构中心数量 : 0
  • 不确定化学键立构中心数量 : 0
  • 共价键单元数量 : 3
  • 疏水参数计算参考值(XlogP) : 无
  • 互变异构体数量 : 无
  • 表面电荷 : 0
  • 拓扑分子极性表面积 : 0

溴化镉(7789-42-6)安全信息

溴化镉(7789-42-6)国际标准相关数据

EINECS:
232-165-1

溴化镉(7789-42-6)海关数据

海关编码:
2827590000

溴化镉(7789-42-6)生产方法和用途

用途:
用于照相纸板、石版印刷等。
生产方法:
1.将氢溴酸加到金属镉中,再加过量的溴水。 当金属镉大部分溶解后,滤去未溶的镉,所得滤液加热蒸发至接近饱和,在0oC冷却结晶,分离出的结晶用水进行重结晶,即为四水合溴化镉。在真空条件下干燥,则可得无水溴化镉。2.将金属镉置于石英舟中,放入充满干燥氮气的耐热玻璃管内。在450℃的温度下,用氮气通过一个盛有Br2的洗瓶,把Br2带到石英舟上与Cd进行溴化反应。要使3g金属镉完全反应掉,需约2h。如果想要提高反应温度来加快溴化反应是不可取的,因为反应温度提高会有金属镉及产品被蒸发掉。当产物出现持续亮黄色时,反应结束。把CdBr2在Br2气氛中蒸馏二次,然后使CdBr2熔化,用纯的CO2脱除过量的Br2,即可获得无水溴化镉。3.将CdBr2·4H2O(制备方法见CdBr2·4H2O制法)的晶体置于装有氢氧化钾的减压干燥器中干燥,即可得无水溴化镉。

溴化镉(7789-42-6)推荐厂家 更多厂家(21)

溴化镉(7789-42-6)相关文献

溴化镉(7789-42-6)参考资料

Reaxys RN:
PubChem CID:

溴化镉(7789-42-6) MSDS

基础信息


Section 1: Product Identification
   Chemical Name:       Cadmium bromide, anhydrous, 99%    
   CAS Registry Number:       7789-42-6    
   Formula:       CdBr2    
   EINECS Number:       232-165-1    
   Chemical Family:       metal halide    
   Synonym:       Cadmium dibromide    

Section 2: Composition and Information on Ingredients
   Ingredient       CAS Number       Percent       ACGIH (TWA)       OSHA (PEL)    
   Title Compound       7789-42-6       100%       0.002mg/m3       0.005mg/m3    

Section 3: Hazards Identification
   Irritating to skin, eyes and respiratory tract. Harmful by inhalation, in contact with skin and if swallowed. May
   Emergency Overview:
   cause cancer.
   Primary Routes of Exposure:       Ingestion, inhalation    
   Eye Contact:       Causes mild to severe irritant to the eyes.    
   Skin Contact:       Causes slight to mild irritation of the skin.    
   irritating to the respiratory tract. Harmful by inhalation. May cause coughing, headache, shortness of breath,
   Inhalation:
   chest pains and pulmonary edema.
   Harmful if swallowed. Ingestion may lead to sudden nausea, vomiting, bloody diarrhea, weakness,
   Ingestion:
   convulsions, and death.
   Harmful by inhalation, in contact with skin and if swallowed. irritating to skin, eyes and respiratory tract.
   Acute Health Affects:
   Ihalation may cause metallic taste, cough, chest pain, pulmonary edema, liver and kidney damage.
   Prolonged exposure may cause loss of sense of smell, weight loss, liver, lung, skeletal and kidney damage.
   Chronic Health Affects:
   Cadmium is a recognized carcinogen of the connective tissue, lungs, and the liver.
   NTP:       Yes    
   IARC:       Yes    
   OSHA:       No    

SECTION 4: First Aid Measures
   Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
   Eye Exposure:
   assistance in keeping their eye lids open. Get immediate medical attention.
   Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
   Skin Exposure:
   irritation persists.
   Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
   Inhalation:
   in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
   Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
   Ingestion:
   vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
   Flash Point:       not applicable    
   Autoignition Temperature:       none    
   Explosion Limits:       none    
   Extinguishing Medium:       none required    
   Special Fire Fighting Procedures:       No special fire fighting procedures required.    
   Hazardous Combustion and       Toxic dusts contain cadmium    
   Decomposion Products:
   Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
   Spill and Leak Procedures:       Small spills can be mixed with vermiculite or sodium carbonate and swept up.    

SECTION 7: Handling and Storage
   Handling and Storage:       Store material in a tightly sealed container. Will adsorb moisture if handled in a moist environment.    

SECTION 8: Exposure Controls and Personal Protection
   Eye Protection:       Always wear approved safety glasses when handling a chemical substance in the laboratory.    
   Skin Protection:       Wear appropriate chemical resistant gloves and protective clothing.    
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   In the absence of adequate ventilation a respirator should be worn. The use of a respiratory requires a
   Respirator:
   Respirator Protection Program to be in compliance with 29 CFR 1910.134.
   Ventilation:       Material may form a fine dust. If possible, handle the material in an efficient fume hood.    
   Additional Protection:       No additional protection required.    

SECTION 9: Physical and Chemical Properties
   Color and Form:       white pwdr.    
   Molecular Weight:       272.22    
   Melting Point:       567°    
   Boiling Point:       863°C    
   Vapor Pressure:       no data    
   Specific Gravity:       5.192    
   Odor:       none    
   Solubility in Water:

SECTION 10: Stability and Reactivity
   Stability:       hygroscopic    
   Hazardous Polymerization:       no hazardous polymerization    
   Conditions to Avoid:       contact with moisture    
   Incompatibility:       active metals    
   Decomposition Products:       none    

SECTION 11: Toxicological Information
   RTECS Data:       Oral (rat); LD50: 322 mg/kg. Oral (rat); LD50: 733 mg/kg/90D-C.    
   Carcinogenic Effects:       Carcinogen (as Cd)    
   Mutagenic Effects:       No data available    
   Tetratogenic Effects:       No data available    

SECTION 12: Ecological Information
   Avoid release into the environment. Very toxic to aquatic organisms. May cause long-term adverse effects in
   Ecological Information:
   the aquatic environment.

SECTION 13: Disposal Considerations
   Disposal:       Dispose of according to local, state and federal regulations.    

SECTION 14: Transportation
   Shipping Name (CFR):       Cadmium compounds    
   Hazard Class (CFR):       6.1    
   Additional Hazard Class (CFR):       NA    
   Packaging Group (CFR):       III    
   UN ID Number (CFR):       UN# 2570    
   Shipping Name (IATA):       Cadmium compound    
   Hazard Class (IATA):       6.1    
   Additional Hazard Class (IATA):       NA    
   Packaging Group (IATA):       III    
   UN ID Number (IATA):       UN# 2570    

SECTION 15: Regulatory Information
   TSCA:       Listed in the TSCA inventory.    
   SARA (Title 313):       Title compound see Category Code N078 for reporting.    
   Second Ingredient:       none    


SECTION 16 - ADDITIONAL INFORMATION
N/A