854952-58-2 ((9-苯基-9H-咔唑-3-基)硼酸,B-(9-Phenyl-9H-carbazol-3-yl)boronic Acid)

反应条件：

1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran ; -78 °C; 1 h, -78 °C
1.2 -78 °C; 2 h, -78 °C; -78 °C → rt; overnight, rt; rt → 0 °C
1.3 Reagents: Hydrochloric acid Solvents: Water ; 3 h, 0 °C; 3 h, rt

参考文献：

Synthesis and optoelectronic properties of a novel phosphorescence host material containing carbazole moiety

Peng, Hua-nan; et al, Hecheng Huaxue, 2013, 21(1), 58-61

合成路线：1 步

反应条件：

1.1 Reagents: 1,10-Phenanthroline , Potassium carbonate , Cuprous iodide Solvents: p-Xylene ; 100 °C
1.2 Reagents: N-Bromosuccinimide Solvents: Dimethylformamide ; 0 °C
1.3 Reagents: Butyllithium Solvents: Tetrahydrofuran ; -78 °C
1.4 Reagents: Triisopropyl borate , Hydrochloric acid Solvents: Water ; rt

参考文献：

Synthesis of novel star-shaped carbazole-functionalized triazatruxenes

Feng, Guo-Liang; et al, Tetrahedron Letters, 2006, 47(39), 7089-7092

合成路线：3 步

反应条件：

1.1 Reagents: Potassium hydroxide Catalysts: 1,10-Phenanthroline , Cuprous iodide Solvents: Xylene ; 130 °C
2.1 Reagents: N-Bromosuccinimide Solvents: Chloroform
3.1 Reagents: Butyllithium , Trimethyl borate Solvents: Tetrahydrofuran ; -78 °C

参考文献：

Water-soluble iridium(III) complexes as multicolor probes for one-photon, two-photon and fluorescence lifetime imaging

Ma, Yun; et al, Journal of Organometallic Chemistry, 2023, 992,

合成路线：3 步

反应条件：

1.1 Reagents: Sodium hydroxide Catalysts: 1,10-Phenanthroline , Cuprous iodide Solvents: Xylene ; 48 h, 140 °C
2.1 Reagents: N-Bromosuccinimide Solvents: Chloroform ; rt
3.1 Reagents: Butyllithium ; -78 °C
3.2 Reagents: Trimethyl borate ; -78 °C
3.3 Reagents: Hydrochloric acid Solvents: Water

参考文献：

Color-tunable thiazole-based iridium(III) complexes: Synthesis, characterization and their OLED applications

Chau, Nga-Yuen; et al, Journal of Organometallic Chemistry, 2017, 829, 92-100

合成路线：2 步

1150-62-5

反应条件：

1.1 Reagents: N-Bromosuccinimide Solvents: Chloroform
2.1 Reagents: Butyllithium , Trimethyl borate Solvents: Tetrahydrofuran ; -78 °C

参考文献：

Water-soluble iridium(III) complexes as multicolor probes for one-photon, two-photon and fluorescence lifetime imaging

Ma, Yun; et al, Journal of Organometallic Chemistry, 2023, 992,

合成路线：2 步

1592-95-6

反应条件：

1.1 -
2.1 Reagents: Butyllithium , Trimethyl borate
2.2 Reagents: Hydrochloric acid Solvents: Water

参考文献：

Bipolar host materials comprising carbazole, pyridine and triazole moieties for efficient and stable phosphorescent OLEDs

Zhang, Ting ; et al, Dyes and Pigments, 2021, 192,

合成路线：3 步

108-88-3

反应条件：

1.1 Catalysts: 1,10-Phenanthroline , Potassium hydroxide , Cuprous iodide Solvents: Xylene ; 140 °C
2.1 Reagents: N-Bromosuccinimide Solvents: Dichloromethane
3.1 Reagents: Butyllithium Solvents: Tetrahydrofuran
3.2 Reagents: Trimethyl borate
3.3 Reagents: Hydrochloric acid

参考文献：

Synthesis, characterization, photophysics and electrophosphorescent applications of phosphorescent platinum cyclometalated complexes with 9-arylcarbazole moieties

Ho, Cheuk-Lam; et al, Journal of Organometallic Chemistry, 2009, 694(17), 2735-2749

合成路线：3 步