931-17-9 (1,2-环己二甲醇,Cyclohexane-1,2-diol)

_100%

反应条件：

1.1 Reagents: Water , Oxygen Catalysts: Barium(2+), pentaaqua-, (SP-4-1)-bis[2,5-pyridinedicarboxylato(2-)-κN1,κO2]cupra… Solvents: Acetonitrile ; 2 h, 40 °C

参考文献：

Heterometallic Metal-Organic Frameworks That Catalyze Two Different Reactions Sequentially

Saha, Debraj; Hazra, Dipak K.; Maity, Tanmoy; Koner, Subratanath, Inorganic Chemistry, 2016, 55(12), 5729-5731

合成路线：1 步

_100%

反应条件：

1.1 Reagents: Hydrogen peroxide Catalysts: [[1,1′-Biphenyl]-4,4′-dicarboxylato(2-)-κO4]hydroxyaluminum (coordinated Li/CuCl(THF)) Solvents: Acetonitrile , Water ; 18 h, 80 °C

参考文献：

Chemoselective Oxidation of Alkenes by Metal-Organic Framework-Supported Copper Catalyst

Kalita, Rahul; Begum, Wahida; Gupta, Poorvi; Chauhan, Manav; Akhtar, Naved; et al, European Journal of Inorganic Chemistry, 2023, 26(25),

合成路线：1 步

120-80-9

_100%

反应条件：

1.1 Reagents: Hydrogen Catalysts: Nickel , Cobalt Solvents: Isopropanol ; 4 h, 5 MPa, 100 °C

参考文献：

High surface area biochar from Sargassum tenerrimum as potential catalyst support for selective phenol hydrogenation

Kumar, Adarsh; Kumar, Jitendra; Bhaskar, Thallada, Environmental Research, 2020, 186,

合成路线：1 步

120-80-9

_100%

反应条件：

1.1 Reagents: Hydrogen Solvents: Water ; 2 MPa, rt → 60 °C; 12 h, 60 °C

参考文献：

High efficient hydrogenation of lignin-derived monophenols to cyclohexanols over Pd/γ-Al2O3 under mild conditions

Yi, Jian; Luo, Yiping; He, Ting; Jiang, Zhicheng; Li, Jianmei; et al, Catalysts, 2016, 6(1),

合成路线：1 步

_100%

反应条件：

1.1 Reagents: Water Catalysts: Silica , Titania , Sulfate ; 45 min, 50 °C

参考文献：

Process for preparation of 1,2-cyclohexanediol via hydrolysis of cyclohexene oxide in the presence of solid acid catalyst

, China, , ,

合成路线：1 步

_100%

反应条件：

1.1 Reagents: Water Catalysts: Methanesulfonic acid, 1,1,1-trifluoro-, erbium(3+) salt (3:1) Solvents: Acetonitrile ; 60 min, 25 °C

参考文献：

Erbium(III) triflate is a highly efficient catalyst for the synthesis of β-alkoxy alcohols, 1,2-diols and β-hydroxy sulfides by ring opening of epoxides

Dalpozzo, Renato; Nardi, Monica; Oliverio, Manuela; Paonessa, Rosina; Procopio, Antonio, Synthesis, 2009, (20), 3433-3438

合成路线：1 步

533-60-8

_100%

反应条件：

1.1 Reagents: Tetrabutylammonium borohydride Solvents: 1,2-Dichlorobenzene ; 4 min, 25 °C
1.2 Reagents: Hydrogen peroxide Solvents: Water

参考文献：

Reactivity Control via Dihydrogen Bonding: Diastereoselection in Borohydride Reductions of α-Hydroxyketones

Gatling, Sterling C.; Jackson, James E., Journal of the American Chemical Society, 1999, 121(37), 8655-8656

合成路线：1 步

1792-81-0

_100%

反应条件：

1.1 Reagents: Potassium hydroxide Catalysts: Chloro(η5-indenyl)bis(triphenylphosphine)ruthenium Solvents: Dichloromethane

参考文献：

Efficient catalytic racemization of secondary alcohols

Koh, Jeong Hwan; Jeong, Hyun Min; Park, Jaiwook, Tetrahedron Letters, 1998, 39(31), 5545-5548

合成路线：1 步

_100%

反应条件：

1.1 Catalysts: Tungsten zirconium phosphate ((W,Zr)(HPO4)2) Solvents: Acetonitrile ; 48 °C
1.2 Reagents: Hydrogen peroxide Solvents: Water ; 15 min, 48 °C; 21 h, 48 °C

参考文献：

Catalysts for oxidation of olefins and ketones

, World Intellectual Property Organization, , ,

合成路线：1 步

_99%

反应条件：

1.1 Reagents: Carbon dioxide , Water Catalysts: 1H-Imidazolium, 1-ethyl-3-methyl-, salt with 1H-1,2,4-triazole (1:1) ; rt → 140 °C; 3 h, 1 bar, 140 °C

参考文献：

Highly Efficient Hydration of Epoxides under Atmospheric Pressure and Low Water/Epoxide Ratios by a Tunable Azolate Ionic Liquid through Anion-Cation Synergetic Catalysis

Zhao, Zhenyu; Lu, Jiawei; Lin, Wenjun; Wang, Xuming; Bai, Jiayi; et al, Industrial & Engineering Chemistry Research, 2022, 61(44), 16402-16407

合成路线：1 步

120-80-9

_99%

反应条件：

1.1 Reagents: Hydrogen Catalysts: Ruthenium Solvents: Water ; 6 h, 2 MPa, 80 °C
1.2 Reagents: Water ; 0 °C

参考文献：

Ru subnanoparticles on N-doped carbon layer coated SBA-15 as efficient Catalysts for arene hydrogenation

Qian, Wei; Lin, Lina; Qiao, Yunxiang; Zhao, Xiuge; Xu, Zichen; et al, Applied Catalysis, 2019, 585,

合成路线：1 步

4389-22-4

_99%

反应条件：

1.1 Solvents: Water ; 4 h, 140 °C

参考文献：

Method for preparing diol compounds by hydrolyzing cyclic carbonates using ionic liquid as catalyst

, China, , ,

合成路线：1 步

_99%

反应条件：

1.1 Reagents: Water

参考文献：

Manufacture of catechol and its derivatives

, Japan, , ,

合成路线：1 步

_98%

反应条件：

1.1 Reagents: N-methylmorpholine N-oxide Catalysts: Disodium phosphate , Silica , Dipotassium osmate , Poly(allylamine hydrochloride) , 1,4-Bis(9-O-dihydroquinidinyl)phthalazine Solvents: Acetone , Water ; 8 h, rt

参考文献：

Bioinspired Nanoparticle-Assembly Route to a Hybrid Scaffold: Designing a Robust Heterogeneous Catalyst for Asymmetric Dihydroxylation of Olefins

Shilpa, Nagaraju; Manna, Joydeb; Rana, Rohit Kumar, European Journal of Inorganic Chemistry, 2015, 2015(29), 4965-4970

合成路线：1 步

_98%

反应条件：

1.1 Catalysts: Selenious acid , Polystyrene Solvents: Acetonitrile ; 10 min, rt
1.2 Reagents: Hydrogen peroxide Solvents: Water ; 24 h, 30 °C

参考文献：

Method for preparing 1,2-diol by oxidizing olefin under se-containing high polymer catalysis

, China, , ,

合成路线：1 步

_98%

反应条件：

1.1 Reagents: Water Catalysts: (OC-6-12)-[5,10,15,20-Tetraphenyl-21H,23H-porphinato(2-)-κN21,κN22,κN23,κN24]bis… Solvents: Acetonitrile ; 30 min, rt

参考文献：

Investigation of the catalytic activity of an electron-deficient vanadium(IV) tetraphenylporphyrin: A new, highly efficient and reusable catalyst for ring-opening of epoxides

Taghavi, S. Abdolmanaf; Moghadam, Majid; Mohammadpoor-Baltork, Iraj; Tangestaninejad, Shahram; Mirkhani, Valiollah; et al, Polyhedron, 2011, 30(13), 2244-2252

合成路线：1 步

_98%

反应条件：

1.1 Reagents: Water Catalysts: Ferric sulfate , Poly(oxy-1,2-ethanediyl), α-[2-[1-(3-sulfopropyl)-1H-imidazolium-3-yl]ethyl]-ω-[… Solvents: Toluene , Water ; 2 h, 110 °C

参考文献：

Facile and efficient hydrolysis of organic halides, epoxides, and esters with water catalyzed by ferric sulfate in a PEG1000-DAIL[BF4]/toluene temperature-dependent biphasic system

Hu, Yu Lin; Jiang, Hui; Zhu, Jie; Lu, Ming, New Journal of Chemistry, 2011, 35(2), 292-298

合成路线：1 步

_98%

反应条件：

1.1 Reagents: Water Solvents: Water

参考文献：

Preparation of cyclohexane-1,2-diol and alkyl-substituted cyclopentane-1,2-diol by the hydration of their corresponding oxides

Mekhtiev, S. D.; Musaev, M. R.; Guseinova, E. S.; Mamedov, F. M., Vopr. Neftekhim., 1977, 9, 35-9

合成路线：1 步

_97%

反应条件：

1.1 Reagents: Hydrogen peroxide Solvents: Acetonitrile ; 10 h, 80 °C

参考文献：

Polystyrene selenization method using diselenide as selenium source

, China, , ,

合成路线：1 步

_97%