934329-77-8 (2-(BENZOFURAN-6-YL)-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE,2-(BENZOFURAN-6-YL)-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE)

_82%

反应条件：

1.1 Reagents: Potassium acetate Catalysts: [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium Solvents: 1,4-Dioxane ; 12 h, 130 °C

参考文献：

Ni-Catalyzed Reductive Dibenzylation of Trifluoromethylalkenes for CF3-Containing All-Carbon Quaternary Center Construction

Chen, Kai; Liu, Qian; Wan, Jinyan; Zhu, Chuan; Feng, Chao, Organic Letters, 2023, 25(32), 5995-6000

合成路线：1 步

反应条件：

1.1 Reagents: Potassium acetate Catalysts: [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium Solvents: 1,2-Dimethoxyethane ; overnight, 80 °C

参考文献：

Preparation of five membered heterocyclic compounds as STING agonists

, China, , ,

合成路线：1 步

反应条件：

1.1 Reagents: Potassium acetate Catalysts: [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium Solvents: Acetonitrile ; rt → 60 °C; 16 h, 60 °C

参考文献：

Pyrimidine sulfamide derivative, preparation method and medical application thereof

, World Intellectual Property Organization, , ,

合成路线：1 步

反应条件：

1.1 Reagents: Potassium acetate Catalysts: [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium Solvents: 1,4-Dioxane ; 12 h, 130 °C

参考文献：

Electroluminescent material based on indole-derivative host and iridium compound dopant for organic electroluminescent device

, Korea, , ,

合成路线：1 步

反应条件：

1.1 Reagents: Potassium acetate Catalysts: [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium Solvents: 1,4-Dioxane ; 12 h, 130 °C

参考文献：

Preparation of indole-based compounds as organic electroluminescent materials

, World Intellectual Property Organization, , ,

合成路线：1 步

227752-25-2

反应条件：

1.1 Reagents: Potassium acetate Catalysts: 1,1-Bis(diphenylphosphino)ferrocene , [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium Solvents: 1,4-Dioxane ; 38 h, 80 °C

参考文献：

Preparation of 4-carboxypyrazoles as antivirals for treatment of hepatitis C virus (HCV) infection

, World Intellectual Property Organization, , ,

合成路线：1 步

反应条件：

1.1 Reagents: Butyllithium Solvents: Diethyl ether ; 1 h, -78 °C; -78 °C → -30 °C; -30 °C → -78 °C
1.2 Reagents: Trimethyl borate ; -78 °C; overnight, -78 °C → rt
1.3 Reagents: Hydrochloric acid Solvents: Water ; rt
1.4 Solvents: Dichloromethane ; 4 h, reflux

参考文献：

Nanomolar competitive inhibitors of Mycobacterium tuberculosis and Streptomyces coelicolor type II dehydroquinase

Prazeres, Veronica F. V.; Sanchez-Sixto, Cristina; Castedo, Luis; Lamb, Heather; Hawkins, Alastair R.; et al, ChemMedChem, 2007, 2(2), 194-207

合成路线：1 步

反应条件：

1.1 Reagents: Potassium acetate Catalysts: [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium Solvents: Dimethyl sulfoxide ; 18 h, rt → 80 °C

参考文献：

4-Amino-6-heterocyclylpicolinates and 6-amino-2-heterocyclylpyrimidinecarboxylates

, World Intellectual Property Organization, , ,

合成路线：1 步

参考文献：

4-Amino-6-heterocyclylpicolinates and 6-amino-2-heterocyclylpyrimidinecarboxylates

, United States, , ,

合成路线：2 步

62810-43-9