939430-30-5 (3-(3-吡啶)苯硼酸频那醇酯,3-(3-pyridinyl)phenylboronic acid pinacol ester)

_95%

反应条件：

1.1 Reagents: Potassium acetate Catalysts: Tricyclohexylphosphine , Bis(dibenzylideneacetone)palladium Solvents: 1,4-Dioxane ; 24 h, 85 °C

参考文献：

Preparation of triphenylpyrimidine core containing compounds and applications in organic electroluminescent diode

, China, , ,

合成路线：1 步

4373-60-8

_95%

反应条件：

1.1 Reagents: Potassium acetate Catalysts: Tricyclohexylphosphine , Tris(dibenzylideneacetone)dipalladium Solvents: 1,4-Dioxane ; 24 h, 85 °C

参考文献：

A compound with tripyridylbenzene as core, and the preparation method and application thereof

, China, , ,

合成路线：1 步

_95%

反应条件：

1.1 Reagents: Potassium acetate , Tricyclohexylphosphine Catalysts: Tris(dibenzylideneacetone)dipalladium Solvents: 1,4-Dioxane ; 24 h, 85 °C

参考文献：

Compound using pyridine as nucleus and its preparation method and application

, China, , ,

合成路线：1 步

_95%

反应条件：

1.1 Reagents: Potassium acetate Catalysts: Tricyclohexylphosphine , Bis(dibenzylideneacetone)palladium Solvents: 1,4-Dioxane ; 72 h, 80 °C

参考文献：

Organic electroluminescence element containing heteroaryl compound having novel biphenyl center backbone

, Japan, , ,

合成路线：1 步

_95%

反应条件：

1.1 Reagents: Potassium acetate Catalysts: Tricyclohexylphosphine , Bis(dibenzylideneacetone)palladium Solvents: 1,4-Dioxane ; 72 h, 80 °C; 80 °C → rt

参考文献：

Novel Four-Pyridylbenzene-Armed Biphenyls as Electron-Transport Materials for Phosphorescent OLEDs

Su, Shi-Jian; Tanaka, Daisaku; Li, Yan-Jun; Sasabe, Hisahiro; Takeda, Takashi; et al, Organic Letters, 2008, 10(5), 941-944

合成路线：1 步

_94%

反应条件：

1.1 Reagents: Potassium acetate Catalysts: 1,1-Bis(diphenylphosphino)ferrocene , [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium Solvents: 1,4-Dioxane

参考文献：

Synthesis, characterization and molecular recognition of a bis-platinum terpyridine dimer

Trokowski, Robert; Akine, Shigehisa; Nabeshima, Tatsuya, Chemical Communications (Cambridge, 2008, (7), 889-890

合成路线：1 步

_92%

反应条件：

1.1 Reagents: Potassium acetate Catalysts: [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium Solvents: 1,4-Dioxane ; 80 °C

参考文献：

Tuning Energy Levels of Electron-Transport Materials by Nitrogen Orientation for Electrophosphorescent Devices with an 'Ideal' Operating Voltage

Su, Shi-Jian; Sasabe, Hisahiro; Pu, Yong-Jin; Nakayama, Ken-ichi; Kido, Junji, Advanced Materials (Weinheim, 2010, 22(30), 3311-3316

合成路线：1 步

_90%

反应条件：

1.1 Reagents: Potassium acetate Catalysts: Palladium diacetate , 2-Dicyclohexylphosphino-2′,6′-dimethoxybiphenyl Solvents: Acetone , Tetrahydrofuran ; overnight, 60 °C

参考文献：

Electron-transporting materials based on phenyl pyridine derivatives and optoelectronic devices employing the electron-transporting materials

, World Intellectual Property Organization, , ,

合成路线：1 步

_90%

反应条件：

1.1 Reagents: Potassium acetate Catalysts: Palladium diacetate , 2-Dicyclohexylphosphino-2′,6′-dimethoxybiphenyl Solvents: Tetrahydrofuran , 1,4-Dioxane ; 15 h, reflux

参考文献：

Compounds comprising phenyl and pyridine units and optoelectronic devices using them

, United States, , ,

合成路线：1 步

_89%

反应条件：

1.1 Reagents: Potassium acetate Catalysts: [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium Solvents: Toluene ; 6 h, reflux

参考文献：

Pyridine derivative compound as electroluminescent material for organic electroluminescent device

, Korea, , ,

合成路线：1 步

1565857-71-7

626-55-1

_88%

反应条件：

1.1 Catalysts: Tetrakis(triphenylphosphine)palladium Solvents: Toluene ; 12 h, 110 °C; 110 °C → rt

参考文献：

Synthesis of Trimethylstannyl Arylboronate Compounds by Sandmeyer-Type Transformations and Their Applications in Chemoselective Cross-Coupling Reactions

Qiu, Di; Wang, Shuai; Tang, Shengbo; Meng, He; Jin, Liang; et al, Journal of Organic Chemistry, 2014, 79(5), 1979-1988

合成路线：1 步

_88%

反应条件：

1.1 Reagents: Potassium acetate Catalysts: Tricyclohexylphosphine , Bis(dibenzylideneacetone)palladium Solvents: 1,4-Dioxane ; 72 h, 80 °C

参考文献：

Pyridylterphenyl derivatives for electron transport materials in organic electroluminescence devices

, Japan, , ,

合成路线：1 步

_83%