97042-18-7 (4-[[4-(2-烯丙氧基)苯基]磺酰基]苯酚,4-4-(prop-2-en-1-yloxy)benzenesulfonylphenol)

_98%

反应条件：

1.1 Reagents: Sodium hydroxide Catalysts: Tetrabutylammonium iodide , Sodium iodide Solvents: Methanol , Water ; rt → 78 °C; 2 h, 78 °C
1.2 Reagents: Hydrochloric acid Solvents: Water ; pH 7

参考文献：

Production process for improving reaction rate and yield of bisphenol S monoallyl ether

, China, , ,

合成路线：1 步

_96%

反应条件：

1.1 Catalysts: Tetrabutylammonium iodide , Sodium iodide Solvents: Ethanol , Water ; 2 h, rt → 80 °C
1.2 Reagents: Hydrochloric acid Solvents: Water ; 80 °C → 25 °C; 2 h, 25 °C

参考文献：

Chemical synthesis of bisphenol S monoallyl ether from bisphenol S and chloropropylene

, China, , ,

合成路线：1 步

_94%

反应条件：

1.1 Reagents: Sodium hydroxide Solvents: Water ; 8 h, 0.8 - 1 kg/cm2, 55 - 60 °C; 1 h, 80 °C
1.2 85 - 90 °C
1.3 Reagents: Sulfuric acid Solvents: Water ; pH 8.9, 90 °C → 35 °C

参考文献：

Production of diphenyl sulfone compounds

, World Intellectual Property Organization, , ,

合成路线：1 步

_79%

反应条件：

1.1 Reagents: Triethylamine Solvents: Tetrahydrofuran ; rt → 50 °C
1.2 Solvents: Tetrahydrofuran ; 2 h, 50 °C; 4 h, 50 °C

参考文献：

Enhanced Properties of the Incorporation of a Novel Reactive Phosphorus- and Sulfur-Containing Flame-Retardant Monomer into Unsaturated Polyester Resin

Dai, Kang; Song, Lei; Yuen, Richard K. K.; Jiang, Saihua; Pan, Haifeng; et al, Industrial & Engineering Chemistry Research, 2012, 51(49), 15918-15926

合成路线：1 步

41481-63-4

_15%

反应条件：

1.1 Reagents: Hydrochloric acid

参考文献：

Synthesis and biological activity of some ethers of 4,4'-dihydroxydiphenyl sulfone

Pisanenko, D. A.; Novikov, I. N.; Grib, O. K.; Abramova, K. A.; Smirnov-Zamkov, Yu. I.; et al, Vestn. Kiev. Politekhn. In-ta. Khim. Mashinostr. i Tekhnol., 1984, (21), 25-8

合成路线：1 步

反应条件：

1.1 Reagents: Sodium hydroxide Solvents: Water ; 4 h, 55 °C; 3 h, 55 - 65 °C; 65 °C → 80 °C
1.2 Reagents: Hydrochloric acid Solvents: Water ; pH 9

参考文献：

Thermal printing material containing sensitizer

, Japan, , ,

合成路线：1 步

反应条件：

1.1 Catalysts: Potassium hydroxide , Sodium hydroxide Solvents: Water ; 100 °C; 100 °C → 70 °C
1.2 6 h, 65 - 70 °C; 3 h, 65 - 70 °C

参考文献：

Preparation of 4-hydrocarbyloxy-4'-hydroxydiphenyl sulfones

, Japan, , ,

合成路线：1 步

反应条件：

1.1 Reagents: Sodium hydroxide Solvents: Water ; 3 h, 60 °C
1.2 Reagents: Sodium hydroxide Solvents: Water ; 1 h, pH 12, 80 °C
1.3 Reagents: Sulfuric acid Solvents: Water ; 1 h, pH 9, 80 °C; 1 h, 30 °C

参考文献：

Developing substance for heat-sensitive recording and the heat-sensitive recording material

, Japan, , ,

合成路线：1 步

反应条件：

1.1 Reagents: Sodium hydroxide , Sodium chloride ; 6 h, 60 °C; 9 h, 60 °C
1.2 Reagents: Sulfuric acid Solvents: Water ; pH 1, 60 °C; 1 h, 80 °C; 1 h, 65 °C

参考文献：

Preparation of high-purity 4,4'-dihydroxydiphenyl sulfone monoethers

, Japan, , ,

合成路线：1 步

反应条件：

1.1 Reagents: Potassium carbonate , Potassium hydroxide Solvents: 1,2-Dichlorobenzene , Water ; rt → 90 °C; 15 h, 90 - 100 °C

参考文献：

Preparation of high-purity dihydroxydiphenyl sulfone monoethers as color developers for thermal printing materials

, Japan, , ,

合成路线：1 步

反应条件：

1.1 Reagents: Sodium hydroxide Solvents: Water

参考文献：

Process for producing diphenyl sulfone compounds

, World Intellectual Property Organization, , ,

合成路线：1 步