97-94-9 (三乙基硼,Triethylborane (1.0 M in THF))

_100%

反应条件：

1.1 Reagents: Magnesium , Iodine Solvents: Butyl ether ; 2 h, cooled; 2 h, 40 °C

参考文献：

Method for preparing triethyl boron with high yield by controlling key conditions

, China, , ,

合成路线：1 步

_96%

反应条件：

1.1 Reagents: (Dimethyl sulfide)trihydroboron Solvents: Tetrahydrofuran ; 10 - 12 h, -50 - 30 °C

参考文献：

Method for preparing high-purity borane gas and application of the borane gas

, China, , ,

合成路线：1 步

_93%

反应条件：

1.1 Reagents: Boron trifluoride etherate , Magnesium Solvents: Diethyl ether ; 10 h, reflux; 3 h, reflux

参考文献：

Method for preparing lithium triethylborohydride tetrahydrofuran solution

, South Africa, , ,

合成路线：1 步

_93%

反应条件：

1.1 Reagents: Boron trifluoride etherate , Magnesium Solvents: Diethyl ether ; 10 h, reflux; 3 h, reflux; reflux → 150 °C; 150 °C

参考文献：

Method for preparing tetrahydrofuran solution of triethyl lithium borohydride

, China, , ,

合成路线：1 步

15221-30-4

150-46-9

_90%

参考文献：

Ultrasonic irradiation in one-pot synthesis of triethylaluminum etherate and its conversion into other organometallic compounds

Lin, Yih Tsung, Journal of Organometallic Chemistry, 1986, 317(3), 277-83

合成路线：1 步

97-93-8

_78%

反应条件：

1.1 Reagents: Tributoxyboroxin

参考文献：

Preparation of trialkylboranes

, Japan, , ,

合成路线：1 步

_42%

反应条件：

1.1 Reagents: (T-4)-Trifluoro[oxybis[methane]]boron , Magnesium , Iodine Solvents: Diethylene glycol dibutyl ether ; 2 h, rt; 2 h, 50 °C

参考文献：

Part 2. Mechanistic aspects of the reduction of S-alkyl-thionocarbonates in the presence of triethylborane and air

Allais, Florent; Boivin, Jean; Nguyen, Van Tai, Organic Chemistry, 2011, , 161-170

合成路线：1 步

参考文献：

Product subclass 38: trialkylboranes

Zaidlewicz, M.; Krzeminski, M., Science of Synthesis, 2004, 6, 1097-1215

合成路线：1 步

反应条件：

1.1 Reagents: Borane Solvents: Tetrahydrofuran ; 5 h, -5 - 20 °C

参考文献：

Industrial production method for high-activity borane compound

, World Intellectual Property Organization, , ,

合成路线：1 步

反应条件：

1.1 Reagents: (T-4)-Trihydro(tetrahydrofuran)boron Solvents: Tetrahydrofuran ; 0 °C; 3 h, rt

参考文献：

Generation of Organolithium Compounds bearing Super Silyl Ester and their Application to Matteson Rearrangement

Oda, Susumu; Yamamoto, Hisashi, Angewandte Chemie, 2013, 52(31), 8165-8168

合成路线：1 步

参考文献：

Synthesis of alkanols by carbonylation reactions

Ilyashenko, G.; Schuetz, T.; Whiting, A., Science of Synthesis, 2008, 36, 245-254

合成路线：1 步

557-20-0

参考文献：

Product subclass 26: aryl- and hetarylboranes

Miyaura, N., Science of Synthesis, 2004, 6, 677-696

合成路线：1 步

125878-72-0

参考文献：

Boron compounds. 98. Organo-substituted 2,5-dihydro-1,2,5-oxoniasilaboratoles - characterization and reactivity

Koester, Roland; Seidel, Guenter; Wrackmeyer, Bernd, Chemische Berichte, 1991, 124(5), 1003-16

合成路线：1 步

5518-25-2

反应条件：

1.1 Catalysts: Triphenyl phosphite

参考文献：

Boron compounds. 75. Reactions of (organo)phosphorus-oxygen compounds with diorgano-hydro-boranes

Koester, Roland; Schuessler, Wilhelm; Synoradzki, Ludwik, Chemische Berichte, 1987, 120(7), 1105-15

合成路线：1 步

反应条件：

1.1 Reagents: Borane Solvents: Tetrahydrofuran

参考文献：

Chemistry of organoborate. IV. Reaction of lithium thienyltrialkylborate with carbon dioxide

Tang, Yongti; Deng, Minzhi; Xu, Weihua, Huaxue Xuebao, 1986, 44(3), 276-9

合成路线：1 步

688-74-4

反应条件：

1.1 Reagents: Aluminum , Iodine Solvents: Ethanol
1.2 -

参考文献：

Ultrasonic irradiation in the synthesis of triethylborane from ethyl bromide via ethylaluminum sesquibromide

Liou, Kou Fu; Yang, Paw Hwa; Lin, Yih Tsung, Journal of Organometallic Chemistry, 1985, 294(2), 145-9

合成路线：1 步

反应条件：

1.1 Reagents: Boron trifluoride etherate , Magnesium , Iodine Solvents: Diethyl ether

参考文献：

Organoboranes. 44. A convenient, highly efficient synthesis of triorganylboranes via a modified organometallic route

Brown, Herbert C.; Racherla, Uday S., Journal of Organic Chemistry, 1986, 51(4), 427-32

合成路线：1 步

反应条件：

1.1 Reagents: Boron trifluoride etherate , Magnesium Solvents: Diethyl ether

参考文献：

An unusual solvent effect in the reaction of ethylmagnesium bromide with triethylborane in ethyl ether or tetrahydrofuran. A simple direct route to tetraorganylborate complexes

Brown, Herbert C.; Racherla, Uday S., Organometallics, 1986, 5(2), 391-3

合成路线：1 步

98351-43-0

反应条件：

1.1 Solvents: Pentane

参考文献：

Reaction of diethylhydroxyborane with trialkylaluminum

Synoradzki, Ludwik; Boleslawski, Marek; Lewinski, Janusz, Journal of Organometallic Chemistry, 1985, 284(1), 1-4

合成路线：1 步

反应条件：

1.1 Reagents: Diborane

参考文献：

Laser initiated thermal synthesis of triethylborane

Barriola, Antonio; Manzanares I, Carlos; Carlos de Jesus, Juan, Inorganica Chimica Acta, 1985, 98(2),

合成路线：1 步

12081-54-8

参考文献：

Organoboron compounds. 351. NMR study of the thermal transformations of tetraalkyldiboranes

Kuimova, M. E.; Mikhailov, V. M., Izvestiya Akademii Nauk SSSR, 1979, (1979), 314-18

合成路线：1 步

参考文献：

Process of asymmetric hydrogenation of ketals and acetals

, World Intellectual Property Organization, , ,

合成路线：1 步

参考文献：

Stereochemistry of Hexenyl Radical Cyclizations with tert-Butyl and Related Large Groups: Substituent and Temperature Effects

Tripp, Jonathan C.; Schiesser, Carl H.; Curran, Dennis P., Journal of the American Chemical Society, 2005, 127(15), 5518-5527

合成路线：1 步

参考文献：

The catalytic hydroboration of ethylene with diborane in the gas phase. The acidity of catalysts and the reaction activity

Matsuda, Tsuneo; Seto, Isao; Tanaka, Toyosuke, Bulletin of the Chemical Society of Japan, 1976, 49(6), 1713-14

合成路线：1 步

反应条件：

1.1 Reagents: Sulfur dichloride Solvents: Dichloromethane

参考文献：

Selective hydroboration of olefins

Koster, R.; Griaznov, G., Angewandte Chemie, 1961, 73,

合成路线：1 步

反应条件：

1.1 Solvents: Benzene

参考文献：

Boron compounds. XIV. Alkyl-1-alkynylboranes and their tertiary amine complexes

Koester, Roland; Horstschaefer, Heinz J.; Binger, Paul, Justus Liebigs Annalen der Chemie, 1968, 717, 1-20

合成路线：1 步

2603354-43-2

2664885-11-2

参考文献：

Copper-Ligand Cooperativity in H2 Activation Enables the Synthesis of Copper Hydride Complexes

Aloisi, Alicia; Crochet, Etienne; Nicolas, Emmanuel ; Berthet, Jean-Claude ; Lescot, Camille; et al, Organometallics, 2021, 40(13), 2064-2069

合成路线：1 步

反应条件：

1.1 Solvents: Tetrahydrofuran ; 15 min, rt

参考文献：

Recycling a Borate Complex for Synthesis of Polycarbonate Polyols: Towards an Environmentally Friendly and Cost-Effective Process

Patil, Naganath; Bhoopathi, Senthil; Chidara, Vamshi; Hadjichristidis, Nikos; Gnanou, Yves; et al, ChemSusChem, 2020, 13(18), 5080-5087

合成路线：1 步

111-40-0

111-40-0

反应条件：

1.1 Solvents: Tetrahydrofuran ; 1 h, 40 °C

参考文献：

Composite particles, kit, material and method for producing composite particles

, World Intellectual Property Organization, , ,

合成路线：1 步

反应条件：

1.1 Solvents: Toluene , Tetrahydrofuran , Benzene-d6

参考文献：

Lewis acid catalysis: regioselective hydroboration of alkynes and alkenes promoted by scandium triflate

Mandal, Souvik; Verma, Piyush Kumar; Geetharani, K., Chemical Communications (Cambridge, 2018, 54(97), 13690-13693

合成路线：1 步

反应条件：

1.1 -40 °C; 30 min, -40 °C; 15 h, rt

参考文献：

Synthesis of bis(7-octenyl)zinc via heterogeneous Ni catalysts

Chen, Yu; Clark, Thomas P.; Jazdzewski, Brian A.; Klamo, Sara B.; Wenzel, Timothy T., Polyhedron, 2014, 84, 32-36

合成路线：1 步

参考文献：

Product subclass 34: benzylboranes and benzylboronates

Zaidlewicz, M.; Meller, J., Science of Synthesis, 2004, 6, 921-943

合成路线：1 步

97536-02-2