产品货号:C175125
产品名称:(1S)-Camphorsultam
Synonyms:(1S)-(-)-10,2-Camphorsultam; (2R)-Bornane-10,2-sultam; Hexahydro-8,8-dimethyl-3H-3a,6-methano-2,1-benzisothiazole;
CAS号:94594-90-8
分子式:C₁₀H₁₇NO₂S
Appearance:White Solid
Melting Point:170-173˚C
分子量:215.13
Storage:4°C
Solubility:Chloroform, Ethanol, Methanol
Category:Building Blocks; Chiral Molecules;
应用:(1S)-Camphorsultam is used as a chiral auxiliary to control the stereochemistry in order to obtain the desired stereoselective product. It’s also a reagent used to make Camphorsultam conjugates, and used as a catalyst with the help of a lewis acid in organic reactions such as the Diels-Alder reaction, and the Grignard reaction.
参考文献:Springthorpe, B., et al.: Bioorg. Med. Chem. Lett., 17, 6013 (2007); Inoue, M., et al.: Nat. Chem., 2, 280 (2010); Chapuis, C., et al.: Pol. J. Chem., 68, 2323-31 (1994); Merhcan, F.L., et al.: Tetrahedron: Asymmetry, 7, 667-70 (1996);
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