6863-58-7 (仲丁基醚,Butane, 2,2'-oxybis-)

CAS号:
6863-58-7
中文名称:
仲丁基醚
英文名称:
Butane, 2,2'-oxybis-
安全信息:
分子式:
C8H18O
分子量:
130.227922916412
简介:
库房通风低温干燥; 与氧化剂,食品原料分开存,遇热, 明火, 氧化剂易燃; 热分解排出有毒辛辣刺激烟雾。

仲丁基醚(6863-58-7)名称与标识符

名称

中文别名:
仲丁基醚;仲丁醚(外消旋和内消旋的混合物);仲丁醚(外消旋和内消旋的混合物)(含稳定剂氢醌);3-羟基-2-甲基吡啶;sec-Butyl Ether (DL- and meso- mixture)(stabilized with HQ) 仲丁醚(外消旋和内消旋的混合物)(含稳定剂氢醌);仲丁基醚;仲丁醚;双(2-丁基)醚;异氰酸苯磺酰酯;
英文别名:
Butane, 2,2'-oxybis-;sec-Butyl Ether (DL- and meso- mixture)(stabilized with HQ);2,2'-Oxybisbutane;2-butan-2-yloxybutane;sec-Butyl Ether (DL- and meso- mixture);Benzenesulfonyl isocyanate;Di-sec-butyl Ether (DL- and meso- mixture) (stabilized with HQ);Di-sec-Butyl ether;sec-Butyl ether;DTXSID6027636;di-sec. butyl ether;sec-Butyl ether (stab.with HQ);D89852;2-Sec-butoxybutane #;Q29644891;di-s-butyl ether;DB-055172;6863-58-7;MFCD00039921;NCGC00248951-01;BRN 1733014;Propane, 1-methyl-1,1'-oxybis;sec-Butyl ether, 96%;D1405;Bis(2-butyl) ether;NS00021331;8AWU5LAY06;2,2'-oxydibutane;SCHEMBL147241;AKOS015912647;EINECS 229-961-6;CHEMBL3184223;DTXCID207636;0-01-00-00372 (Beilstein Handbook Reference);di (sec-butyl) ether;UNII-8AWU5LAY06;Bis(2-butyl)ether;Tox21_201188;NCGC00258740-01;(sec-C4H9)2O;2-Sec-butoxybutane;CAS-6863-58-7;InChI=1/C8H18O/c1-5-7(3)9-8(4)6-2/h7-8H,5-6H2,1-4H3;Di-sec-butylether;HHBZZTKMMLDNDN-UHFFFAOYSA-;

标识符

MDL:
MFCD00039921
InChIKey:
HHBZZTKMMLDNDN-UHFFFAOYSA-N
Inchi:
InChI=1S/C8H18O/c1-5-7(3)9-8(4)6-2/h7-8H,5-6H2,1-4H3
SMILES:
CCC(C)OC(C)CC

仲丁基醚(6863-58-7)物化性质

实验特性

  • LogP : 2.60000
  • PSA : 9.23000
  • 折射率 : n20/D 1.394(lit.)
  • 沸点 : 121°C
  • 熔点 : -100°C
  • 闪点 : 华氏:77 °F
    摄氏:25 °C
  • 密度 : 0.759 g/mL at 25 °C(lit.)

计算特性

  • 精确分子量 : 130.13600
  • 氢键供体数量 : 0
  • 氢键受体数量 : 1
  • 可旋转化学键数量 : 4
  • 同位素质量 : 130.136
  • 重原子数量 : 9
  • 复杂度 : 53.6
  • 同位素原子数量 : 0
  • 确定原子立构中心数量 : 0
  • 不确定原子立构中心数量 : 2
  • 确定化学键立构中心数量 : 0
  • 不确定化学键立构中心数量 : 0
  • 共价键单元数量 : 1
  • 疏水参数计算参考值(XlogP) : 2.7
  • 互变异构体数量 : 无
  • 表面电荷 : 0
  • 拓扑分子极性表面积 : 9.2A^2

仲丁基醚(6863-58-7)国际标准相关数据

EINECS:
229-961-6

仲丁基醚(6863-58-7)海关数据

海关编码:
2909199090
海关数据:

中国海关编码:

2909199090

概述:

2909199090. 其他无环醚及其卤化衍生物(包括磺化,硝化或亚硝化衍生物). 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%

申报要素:

品名, 成分含量, 用途

Summary:

2909199090. other acyclic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

仲丁基醚(6863-58-7)推荐厂家 更多厂家(36)

仲丁基醚(6863-58-7)合成路线

合成路线:1 步
反应条件:
参考文献:
Production of biomass-derived furanic ethers and levulinate esters using heterogeneous acid catalysts
Neves, Patricia; et al, Green Chemistry, 2013, 15(12), 3367-3376

仲丁基醚(6863-58-7)相关文献

仲丁基醚(6863-58-7)参考资料

Reaxys RN:
1733014
Beilstein:
1(3)1533
PubChem CID:

仲丁基醚(6863-58-7) MSDS

基础信息

  sec-Butyl Ether (DL- and meso- mixture) (stabilized with Revision number: 6
  HQ)
  SAFETY DATA SHEET

Section 1. IDENTIFICATION
  Product name:        sec-Butyl Ether (DL- and meso- mixture) (stabilized with HQ)    
                  
  Revision number:        6    

Section 2. HAZARDS IDENTIFICATION
  GHS classification
  PHYSICAL HAZARDS
    Category 3
  Flammable liquids
  HEALTH HAZARDS        Not classified    
    Not classified
  ENVIRONMENTAL HAZARDS
  GHS label elements, including precautionary statements
  Pictograms or hazard symbols
  Signal word        Warning    
    Flammable liquid and vapour
  Hazard statements
  Precautionary statements:
    Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
  [Prevention]
    Keep container tightly closed.
    Use explosion-proof electrical/ventilating/lighting equipment. Take precautionary
    measures against ignition by the static discharge and the spark.
    Wear protective gloves/eye protection/face protection.
  [Response]        IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse    
    skin with water/shower.
  [Storage]        Store in a well-ventilated place. Keep cool.    
  [Disposal]        Dispose of contents/container through a waste management company authorized by    
    the local government.
  Other hazards which do not        May cause polimerization.    
  result in classification

Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
  Substance/mixture:        Substance    
    sec-Butyl Ether (DL- and meso- mixture) (stabilized with HQ)
  Components:
  Percent:        >97.0%(GC)    
    6863-58-7
  CAS Number:
  Synonyms:        Di-sec-butyl Ether (DL- and meso- mixture) (stabilized with HQ)    
  Chemical Formula:        C8H18O    
  sec-Butyl Ether (DL- and meso- mixture)
  (stabilized with HQ)

Section 4. FIRST AID MEASURES
  Inhalation:        Remove victim to fresh air and keep at rest in a position comfortable for breathing.    
    Get medical advice/attention if you feel unwell.
  Skin contact:        Remove/Take off immediately all contaminated clothing. Rinse skin with    
    water/shower. If skin irritation or rash occurs: Get medical advice/attention.
  Eye contact:        Rinse cautiously with water for several minutes. Remove contact lenses, if present    
    and easy to do. Continue rinsing. If eye irritation persists: Get medical
    advice/attention.
  Ingestion:        Get medical advice/attention if you feel unwell. Rinse mouth.    
    A rescuer should wear personal protective equipment, such as rubber gloves and air-
  Protection of first-aiders:
    tight goggles.

Section 5. FIRE-FIGHTING MEASURES
  Suitable extinguishing        Dry chemical, foam, carbon dioxide.    
  media:
  Unsuitable extinguishing Water (It may scatter and spread fire.)
  media:
  Specific hazards arising This substance may polimerize explosively when heated or involved in a fire.
  from the chemical:        Container may explode when heated. Combat fire from a sheltered position.    
  Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
    method according to the surrounding situation is used. Uninvolved persons should
    evacuate to a safe place. In case of fire in the surroundings: Keep containers cool by
    spraying with water. Eliminate all ignition sources if safe to do so.
  Special protective        When extinguishing fire, be sure to wear personal protective equipment.    
  equipment for firefighters:

Section 6. ACCIDENTAL RELEASE MEASURES
  Personal precautions,        Use personal protective equipment. Keep people away from and upwind of spill/leak.    
  protective equipment and Ensure adequate ventilation. Entry to non-involved personnel should be controlled
  emergency procedures: around the leakage area by roping off, etc.
  Environmental precautions: Prevent product from entering drains.
  Methods and materials for Absorb spilled material in dry sand or inert absorbent before recovering it into a
  containment and cleaning covered container. In case of large amount of spillage, contain a spill by bunding.
  up: Adhered or collected material should be promptly disposed of, in accordance with
    appropriate laws and regulations.
  Prevention of secondary Remove all sources of ignition. Fire-extinguishing devices should be prepared in
  hazards:        case of a fire. Use spark-proof tools and explosion-proof equipment.    

Section 7. HANDLING AND STORAGE
  Precautions for safe handling
  Technical measures:        Handling is performed in a well ventilated place. Wear suitable protective equipment.    
    Prevent generation of vapour or mist. Keep away from heat/sparks/open flame/hot
    surfaces. -No smoking. Take measures to prevent the build up of electrostatic
    charge. Use explosion-proof equipment. Wash hands and face thoroughly after
    handling.
    Use a closed system if possible. Use a ventilation, local exhaust if vapour or aerosol
    will be generated.
  Advice on safe handling: Avoid contact with skin, eyes and clothing.
  Conditions for safe storage, including any
  incompatibilities
  Storage conditions:        Keep container tightly closed. Store in a cool, dark and well-ventilated place.    
    Store away from incompatible materials such as oxidizing agents.
  Packaging material:        Comply with laws.    

Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
  Engineering controls:        Install a closed system or local exhaust. Also install safety shower and eye bath.    
  sec-Butyl Ether (DL- and meso- mixture)
  (stabilized with HQ)

Section 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
  Personal protective equipment
  Respiratory protection: Vapor respirator. Follow local and national regulations.
  Hand protection:        Protective gloves.    
    Safety glasses. A face-shield, if the situation requires.
  Eye protection:
  Skin and body protection: Protective clothing. Protective boots, if the situation requires.

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
  Physical state (20°C):        Liquid    
    Clear
  Form:
  Colour:        Colorless - Almost colorless    
    No data available
  Odour:
  pH: No data available
  Melting point/freezing point:No data available
  Boiling point/range:        121°C    
  Flash point:        26°C    
  Flammability or explosive
  limits:
  Lower:        No data available    
  Upper:        No data available    
  Relative density:        0.76    
  Solubility(ies):
  [Water]        No data available    
    No data available
  [Other solvents]

Section 10. STABILITY AND REACTIVITY
  Chemical stability:        Polymerization may occur under the influences of heat, light or on contact with    
    polymelization initiators such as peroxides etc.
  Possibility of hazardous No special reactivity has been reported.
  reactions:
    Heat, Spark, Open flame, Static discharge, Light
  Conditions to avoid:
  Incompatible materials: Oxidizing agents
  Hazardous decomposition Carbon monoxide, Carbon dioxide
  products:

Section 11. TOXICOLOGICAL INFORMATION
    ihl-mus LC50:130 g/m3/15M
  Acute Toxicity:
  Skin corrosion/irritation: No data available
  Serious eye        No data available    
  damage/irritation:
  Germ cell mutagenicity: No data available
  Carcinogenicity:
    No data available
  IARC =
  NTP =        No data available    
  Reproductive toxicity:        No data available    
  RTECS Number:        EQ2220000    

Section 12. ECOLOGICAL INFORMATION
  Ecotoxicity:
  Fish:        No data available    
  Crustacea:        No data available    
    No data available
  Algae:
  Persistence / degradability: No data available
    No data available
  Bioaccumulative
  potential(BCF):
  Mobility in soil
  Log Pow:        No data available    
  sec-Butyl Ether (DL- and meso- mixture)
  (stabilized with HQ)

Section 12. ECOLOGICAL INFORMATION
  Soil adsorption (Koc): No data available
  Henry's Law        No data available    
  constant(PaM3/mol):

Section 13. DISPOSAL CONSIDERATIONS
    Recycle to process, if possible. Consult your local regional authorities. You may be able to burn in a chemical
    incinerator equipped with an afterburner and scrubber system. Observe all federal, state and local regulations when
    disposing of the substance.

Section 14. TRANSPORT INFORMATION
  Hazards Class:        3: Flammable liquid.    
  UN-No:        1149    
  Proper shipping name:        Dibutyl ethers    
  Packing group:        III    

Section 15. REGULATORY INFORMATION
  Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002
  and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport,
    loading and unloading were prescribed.


SECTION 16 - ADDITIONAL INFORMATION
N/A