930-68-7 (2-环己烯-1-酮,cyclohex-2-en-1-one)

_100%

反应条件：

1.1 Reagents: Hydrogen peroxide , Oxygen Catalysts: Molybdenum dioxide Solvents: Ethanol ; 10 h, 70 °C

参考文献：

Synthesis, characterization and catalytic activity of oleic acid-coated TiO2 nanoparticles carrying MoO2 (acac)2 in the oxidation of olefins and sulfides using economical peroxides

Jafarpour, Maasoumeh; Ghahramaninezhad, Mahboube; Rezaeifard, Abdolreza, New Journal of Chemistry, 2014, 38(7), 2917-2926

合成路线：1 步

_100%

反应条件：

1.1 Reagents: Hydrogen peroxide , Oxygen Catalysts: Molybdenum oxide (MoO3) Solvents: Ethanol ; 12 h, 70 °C

参考文献：

Catalytic activity and selectivity of reusable α-MoO3 nanobelts toward oxidation of olefins and sulfides using economical peroxides

Jafarpour, Maasoumeh; Ghahramaninezhad, Mahboube; Rezaeifard, Abdolreza, RSC Advances, 2014, 4(4), 1601-1608

合成路线：1 步

_100%

反应条件：

1.1 Catalysts: [[2,2′-[(1-Methyl-1,2-ethanediyl)bis[(nitrilo-κN)methylidyne]]bis[4-(2-phenyldia… Solvents: Acetonitrile ; 84 °C

参考文献：

Homogeneous and Heterogeneous Catalytic Activity of Azo-Linked Schiff Base Complexes of Mn(II), Cu(II) and Co(II)

Lashanizadegan, Maryam; Zareian, Zeinab, Catalysis Letters, 2011, 141(11), 1698-1702

合成路线：1 步

_100%

参考文献：

Rapid Iron(III)-Fluoride-Mediated Hydrogen Atom Transfer

Panda, Chakadola ; Doyle, Lorna M. ; Gericke, Robert ; McDonald, Aidan R., Angewandte Chemie, 2021, 60(50), 26281-26286

合成路线：1 步

_100%

反应条件：

1.1 Reagents: tert-Butyl hydroperoxide Catalysts: Ceria , Iron oxide (Fe3O4) , Iron , Silver Solvents: Acetonitrile ; 6 h, 80 °C

参考文献：

Design and Synthesis of Silver Decorated Fe3O4 @ Fe Doped CeO2 Core-Shell Ternary Composite as Highly Efficient Nanocatalyst for Selective Oxidation of Alkenes

Ghosh, Topi; Choudhary, Neha; Mobin, Shaikh M., ChemistrySelect, 2020, 5(31), 9601-9606

合成路线：1 步

_100%

反应条件：

1.1 Reagents: N-Hydroxyphthalimide , Oxygen Catalysts: L-Ascorbic acid (titania-Cobalt- nanohybrid) , Cobalt diacetate , Titania (Cobalt-Ascorbic Acid Nanohybrid) Solvents: Ethyl acetate ; 5 h, 1 atm, 60 °C

参考文献：

Aerobic Stereoselective Oxidation of Olefins on a Visible-Light-Irradiated Titanium Dioxide-Cobalt-Ascorbic Acid Nanohybrid

Jafarpour, Maasoumeh; Feizpour, Fahimeh; Rezaeifard, Abdolreza, Synlett, 2017, 28(2), 235-238

合成路线：1 步

_100%

反应条件：

1.1 Reagents: tert-Butyl hydroperoxide Catalysts: Copper manganese oxide Solvents: Acetonitrile ; 30 min, rt
1.2 Reagents: Oxygen Solvents: Water ; 24 h, 1 atm, rt

参考文献：

Allylic oxidation of cyclic alkenes with molecular oxygen and tert-butyl hydroperoxide over copper-manganese oxides

Zhang, Wu; Wei, Qiuyu; Lan, Lingling; Wu, Aiqun; Yin, Xiuju; et al, Monatshefte fuer Chemie, 2017, 148(2), 357-365

合成路线：1 步

_100%

反应条件：

1.1 Reagents: Hydrogen peroxide , Oxygen Catalysts: L-Ascorbic acid (reaction product with titania and dioxomolybdenum complex) , Titania (reaction product with dioxomolybdenum complex and ascorbic acid) , Bis(acetylacetonato)dioxomolybdenum (reaction product with titania and ascorbic acid) Solvents: Ethanol ; 12 h, 70 °C

参考文献：

Dioxomolybdenum(VI) complex immobilized on ascorbic acid coated TiO2 nanoparticles catalyzed heterogeneous oxidation of olefins and sulfides

Jafarpour, Maasoumeh; Rezaeifard, Abdolreza; Ghahramaninezhad, Mahboube; Feizpour, Fahimeh, Green Chemistry, 2015, 17(1), 442-452

合成路线：1 步

_100%

反应条件：

1.1 Reagents: Oxygen Catalysts: 1H-Imidazolium, 3-decyl-1-methyl-, (OC-6-11)-tris(1,1,1,5,5,5-hexafluoro-2,4-pen… ; 6 h, 1 atm, 60 °C
1.2 Reagents: Triphenylphosphine ; 2 h

参考文献：

Ionic liquids with metal chelate anions

Zhang, Pengfei; Gong, Yutong; Lv, Yiqi; Guo, Yan; Wang, Yong; et al, Chemical Communications (Cambridge, 2012, 48(17), 2334-2336

合成路线：1 步

_100%

反应条件：

1.1 Reagents: Oxygen Catalysts: Osmium Solvents: Toluene ; 80 °C

参考文献：

Osmium(0) nanoclusters stabilized by zeolite framework; highly active catalyst in the aerobic oxidation of alcohols under mild conditions

Zahmakiran, Mehmet; Akbayrak, Serdar; Kodaira, Tetsuya; Oezkar, Saim, Dalton Transactions, 2010, 39(32), 7521-7527

合成路线：1 步

_100%

反应条件：

1.1 Reagents: Oxygen Catalysts: Ruthenium trichloride Solvents: Toluene ; 4 h, 760 torr, rt → 80 °C

参考文献：

Zeolite confined nanostructured dinuclear ruthenium clusters: preparation, characterization and catalytic properties in the aerobic oxidation of alcohols under mild conditions

Zahmakiran, Mehmet; Ozkar, Saim, Journal of Materials Chemistry, 2009, 19(38), 7112-7118

合成路线：1 步

_100%

反应条件：

1.1 Reagents: Iodobenzene diacetate (polystyrene-supported) Catalysts: Tempo (JandaJel resin-supported) Solvents: 1,2-Dichloroethane ; 5 h, 70 °C

参考文献：

A multipolymer system for organocatalytic alcohol oxidation

But, Tracy Yuen Sze; Tashino, Yousuke; Togo, Hideo; Toy, Patrick H., Organic & Biomolecular Chemistry, 2005, 3(6), 970-971

合成路线：1 步

822-66-2

_100%

反应条件：

1.1 Reagents: tert-Butyl hydroperoxide Catalysts: Titanium (silica-bound) Solvents: 2,2,4-Trimethylpentane

参考文献：

A new titanium-silica catalyst for the epoxidation of alkenes

Cativiela, Carlos; Fraile, Jose M.; Garcia, Jose I.; Mayoral, Jose A., Journal of Molecular Catalysis A: Chemical, 1996, 112(2), 259-267

合成路线：1 步

108-94-1

_100%

反应条件：

1.1 Reagents: Chromate(1-), chlorotrioxo-, ammonium, (T-4)- Solvents: Acetonitrile

参考文献：

Oxidation of α-methyl or α-methylene groups in carbonyl compounds with ammonium chlorochromate

Liu, Liangxian; Chen, Mifeng; Cai, Kun, Chinese Chemical Letters, 1992, 3(8), 585-8

合成路线：1 步

_99%

反应条件：

1.1 Catalysts: Palladium , 1,4-Benzenedicarboxylic acid, 2-amino-, copper(2+) salt (1:1) Solvents: Trifluorotoluene ; 3 h, 95 °C

参考文献：

Development of sustainable green catalysts for oxidation of alcohols via decorated palladium nanoparticles on magnetic carbon nanotube/MOF

Keypour, Hassan ; Kouhdareh, Jamal; Alavinia, Sedigheh; Karimi-Nami, Rahman; Karakaya, Idris; et al, Journal of Molecular Structure, 2023, 1294,

合成路线：1 步

_99%

反应条件：

1.1 Reagents: Oxygen Catalysts: N-Hydroxyphthalimide , Copper, [μ-[2,7,12,17,22,27-hexakis(pentafluorophenyl)-31,32,33,34,35,36-hexaaza… Solvents: Acetonitrile ; 7 h, 0.5 MPa, 70 °C

参考文献：

Selective Functionalization of Hydrocarbons Using a ppm Bioinspired Molecular Tweezer via Proton-Coupled Electron Transfer

Chen, Hongyu ; Wang, Lingling; Xu, Sheng; Liu, Xiaohui; He, Qian; et al, ACS Catalysis, 2021, 11(12), 6810-6815

合成路线：1 步

_99%

反应条件：

1.1 Reagents: Oxygen Catalysts: 2,3-Dichloro-5,6-dicyano-1,4-benzoquinone , Nitric acid Solvents: Dichloromethane ; 18 h, rt
1.2 Reagents: Sodium bicarbonate Solvents: Water ; rt

参考文献：

Scalable Aerobic Oxidation of Alcohols Using Catalytic DDQ/HNO3

Katsina, Tania; Clavier, Louis; Giffard, Jean-Francois; Macedo Portela da Silva, Nayane; Fournier, Jean; et al, Organic Process Research & Development, 2020, 24(5), 856-860

合成路线：1 步

_99%

反应条件：

1.1 Reagents: Oxygen Catalysts: 2253137-61-8 Solvents: Acetonitrile , Water ; 18 h, 1 atm, rt

参考文献：

Designing conjugated microporous polymers for visible light-promoted photocatalytic carbon-carbon double bond cleavage in aqueous medium

Ayed, Cyrine; Caire da Silva, Lucas; Wang, Di; Zhang, Kai A. I., Journal of Materials Chemistry A: Materials for Energy and Sustainability, 2018, 6(44), 22145-22151

合成路线：1 步

_99%

反应条件：

1.1 Reagents: Hydrogen peroxide Catalysts: 1-Butanaminium, N,N,N-tributyl-, hydrogen diantimonate(decaaquatetraaluminate)te… Solvents: Acetonitrile , Water ; 2 h, 70 °C

参考文献：

A Lewis acid catalytic core sandwiched by inorganic polyoxoanion caps: selective H2O2-based oxidations with [AlIII4(H2O)10(β-XW9O33H)2]6- (X = AsIII, SbIII)

Carraro, Mauro; Bassil, Bassem S.; Soraru, Antonio; Berardi, Serena; Suchopar, Andreas; et al, Chemical Communications (Cambridge, 2013, 49(72), 7914-7916

合成路线：1 步

_99%

反应条件：

1.1 Reagents: Potassium carbonate , Oxygen Catalysts: Palladium , 1-Methyl-3-(2-phenylethyl)-1H-imidazolium sulfate (1:1) (supported on fibrillated mesoporous carbon) Solvents: Water ; 15 h, 70 °C

参考文献：

A nano-fibrillated mesoporous carbon as an effective support for palladium nanoparticles in the aerobic oxidation of alcohols "on pure water"

Karimi, Babak; Behzadnia, Hesam; Bostina, Mihnea; Vali, Hojatollah, Chemistry - A European Journal, 2012, 18(28),

合成路线：1 步

504-01-8

_80%