932-88-7 (2-碘苯乙炔,(Iodoethynyl)benzene)

快速询单

结构式：

2-碘苯乙炔MOL文件

CAS号：

932-88-7

中文名称：

2-碘苯乙炔

英文名称：

(Iodoethynyl)benzene

安全信息：

分子式：

C₈H₅I

分子量：

228.029774427414

2-碘苯乙炔(932-88-7)名称与标识符

名称

中文别名：

2-碘苯乙炔;

英文别名：

(Iodoethynyl)benzene;2-iodoethynylbenzene;1-(2-iodoethynyl)benzene;1-iodo-2-phenylacetylene;1-Iodo-2-phenylethyne;1-iodophenylacetylene;1-Phenyl-2-iodoethyne;2-Iodo-1-phenylacetylene;Benzene,(iodoethynyl);C8H5I;C9-7-6-8-4-2-1-3-5-8;H1-5;Phenylethynyl iodide;phenyliodoacetylene;(2-Iodoethynyl)benzene (ACI);Benzene, (iodoethynyl)- (7CI, 8CI, 9CI);2-Iodo-1-phenylethyne;Iodo(phenyl)acetylene;NSC 221299;

标识符

InChIKey：

VOHWEKIUKSUIDT-UHFFFAOYSA-N

Inchi：

1S/C8H5I/c9-7-6-8-4-2-1-3-5-8/h1-5H

SMILES：

IC#CC1C=CC=CC=1

2-碘苯乙炔(932-88-7)物化性质

实验特性

LogP : 2.43060
PSA : 0.00000
折射率 : 1.5441 (estimate)
沸点 : 146.45°C (rough estimate)
闪点 : 107.8℃
密度 : 1.8

计算特性

精确分子量 : 227.94400

2-碘苯乙炔(932-88-7)安全信息

符号： GHS07
RTECS号： DA3400000
WGK Germany： 3
安全说明： 26
危险品标志： Xn
危险品运输编号： NONH for all modes of transport
危害声明：H319-H332
警示性声明：P305+P351+P338
储存条件： −20°C
危险类别码： 20-36
信号词： Warning

2-碘苯乙炔(932-88-7)海关数据

海关编码：

2903999090

海关数据：

中国海关编码：

2903999090

概述：

2903999090 其他芳烃卤化衍生物. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:5.5% 普通关税:30.0%

申报要素：

品名, 成分含量, 用途

Summary：

2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

2-碘苯乙炔(932-88-7)推荐厂家更多厂家(6)

公司名称	手机号/电话	联系人	QQ	询单
山东玖玥生物科技有限公司	15553333686	张文杰	643971	询单
上海瀚思化工有限公司	18939883912 021-34536277	顾经理	3003949364	询单
金锦乐（湖南）化学有限公司		金锦乐	1226360695	询单
江苏艾康生物医药研发有限公司	18795912720 025-66061636	杨情情	3004779232	询单
上海颖心实验室设备有限公司	17002132182 021-59178156	墨航琪	3146474380	询单
上海源叶生物科技有限公司	15026964105 15026964105	汤思磊	2881489226	询单
上海阿拉丁生化科技股份有限公司	13167063860 13167063860	阿拉丁	3004013043	询单

2-碘苯乙炔(932-88-7)合成路线

合成路线：1 步

反应条件：

1.1 Catalysts: Carbon nitride (C3N4) Solvents: Dimethylformamide ; 10 min, rt; 24 h, rt

参考文献：

Mesoporous Graphitic Carbon Nitride Photocatalyzed Switchable Divergent Perfluoroalkylation of Terminal Alkynes

Shi, Xiaolin; Song, Tao ; Li, Qinglin; Guo, Xiuling; Yang, Yong, Organic Letters, 2022, 24(47), 8724-8728

合成路线：1 步

536-74-3

_100%

932-88-7

反应条件：

1.1 Reagents: Trimethylsulfonium iodide , Iodobenzene diacetate Solvents: Acetonitrile ; 30 min, rt
1.2 Reagents: Sodium bicarbonate , Sodium thiosulfate Solvents: Water ; rt

参考文献：

Chemoselective and stereospecific iodination of alkynes using sulfonium iodate(I) salt

Rao, Dodla S.; Reddy, Thurpu R.; Kashyap, Sudhir, Organic & Biomolecular Chemistry, 2018, 16(9), 1508-1518

合成路线：1 步

536-74-3

_100%

932-88-7

反应条件：

1.1 Reagents: N-Iodosuccinimide , Potassium hydroxide Solvents: Methanol , Water

参考文献：

Synthesis of highly ethynylated mono and dinuclear Pt(II) tethers bearing the 4,4'-bis(ethynyl)biphenyl (debp) unit as central core

Russo, M. V.; Lo Sterzo, C.; Franceschini, P.; Biagini, G.; Furlani, A., Journal of Organometallic Chemistry, 2001, 619(2), 49-61

合成路线：1 步

536-74-3

_99%

932-88-7

反应条件：

1.1 Reagents: N-Iodosuccinimide , Potassium carbonate Catalysts: Tetrabutylammonium bromide Solvents: Methanol ; rt → 40 °C

参考文献：

Green preparation of 1-iodoalkyne compounds

, China, , ,

合成路线：1 步

536-74-3

_99%

932-88-7

反应条件：

1.1 Solvents: Acetonitrile ; rt

参考文献：

Convenient Access to 2,3-Disubstituted-cyclobut-2-en-1-ones under Suzuki Conditions and Their Synthetic Utility

Alcaide, Benito; Almendros, Pedro ; Lazaro-Milla, Carlos, Chemistry - A European Journal, 2019, 25(31), 7547-7552

合成路线：1 步

536-74-3

_99%

932-88-7

反应条件：

1.1 Reagents: Morpholine , Iodine Solvents: Benzene ; 30 min, rt
1.2 Solvents: Benzene ; rt; 24 h, 45 °C

参考文献：

Scope and Limitations of Palladium-Catalyzed Cross-Coupling Reactions with Organogold Compounds

Hashmi, A. Stephen K.; Doepp, Rene; Lothschuetz, Christian; Rudolph, Matthias; Riedel, Dominic; et al, Advanced Synthesis & Catalysis, 2010, 352(8), 1307-1314

合成路线：1 步

637-44-5

_99%

932-88-7

反应条件：

1.1 Reagents: N-Iodosuccinimide Catalysts: 1-Butanaminium, N,N,N-tributyl-, 2,2,2-trifluoroacetate (1:1) Solvents: Dichloroethane ; 0.25 h, rt

参考文献：

A catalytic halogenation decarboxylation process for the preparation of unsaturated organic halides from organic carboxylic acids and N-haloacidimides

, India, , ,

合成路线：1 步

637-44-5

_99%

932-88-7

反应条件：

1.1 Reagents: N-Iodosuccinimide Catalysts: 1-Butanaminium, N,N,N-tributyl-, 2,2,2-trifluoroacetate (1:1) Solvents: 1,2-Dichloroethane

参考文献：

1-Haloalkynes from Propiolic Acids: A Novel Catalytic Halodecarboxylation Protocol

Naskar, Dinabandhu; Roy, Sujit, Journal of Organic Chemistry, 1999, 64(18), 6896-6897

合成路线：1 步

536-74-3

_98%

932-88-7

反应条件：

1.1 Reagents: N-Iodosuccinimide , Alumina Solvents: Acetonitrile ; rt → 80 °C; 1 h, 80 °C
1.2 Reagents: Sodium thiosulfate Solvents: Water

参考文献：

Efficient synthesis of 1-iodoalkynes via Al2O3 mediated reaction of terminal alkynes and N-iodosuccinimide

Yao, Ming; Zhang, Jingjing; Yang, Sen; Xiong, Hangxing; Li, Li; et al, RSC Advances, 2020, 10(7), 3946-3950

合成路线：1 步

536-74-3

_98%

932-88-7

反应条件：

1.1 Reagents: Morpholine , Iodine Solvents: Benzene ; 30 min, rt
1.2 Solvents: Benzene ; rt; 24 h, rt → 45 °C

参考文献：

Preparation of cis-enamide derivatives in preparation of anti-inflammatory drugs

, China, , ,

合成路线：1 步

536-74-3

_98%

932-88-7

反应条件：

1.1 Reagents: N-Iodosuccinimide Catalysts: Alumina Solvents: Acetonitrile ; 1 h, rt → 80 °C

参考文献：

Preparation method of 1-iodoacetylene

, China, , ,

合成路线：1 步

536-74-3

_98%

932-88-7

反应条件：

1.1 Reagents: Morpholine , Iodine Solvents: Benzene ; 30 min, rt
1.2 Solvents: Benzene ; rt; 24 h, 45 °C

参考文献：

Concise and gram-scale total synthesis of lansiumamides A and B and alatamide

Lin, Ran; Lin, Xi; Su, Qian; Guo, Binbin; Huang, Yanqin; et al, Molecules, 2019, 24(20),

合成路线：1 步

536-74-3

_98%

932-88-7

反应条件：

1.1 Reagents: Benzenesulfonic acid, 4,4′-(1,10-phenanthroline-4,7-diyl)bis-, sodium salt (1:2) Solvents: Acetonitrile ; 5 min, rt
1.2 Reagents: Potassium iodide ; 5 min, rt
1.3 Reagents: Copper sulfate Solvents: Water ; pH 5

参考文献：

Iodination of terminal alkynes using KI/CuSO4 - A facile method with potential for radio-iodination

Ferris, Trevor; Carroll, Laurence; Mease, Ronnie C.; Spivey, Alan C.; Aboagye, Eric O., Tetrahedron Letters, 2019, 60(13), 936-939

合成路线：1 步

13146-23-1

_98%

932-88-7

反应条件：

1.1 Reagents: N-Iodosuccinimide , Benzyl azide Solvents: Dichloromethane

参考文献：

General Method for the Synthesis of 1,4-Disubstituted 5-Halo-1,2,3-triazoles

Gribanov, Pavel S.; Topchiy, Maxim A.; Karsakova, Iuliia V.; Chesnokov, Gleb A.; Smirnov, Alexander Yu.; et al, European Journal of Organic Chemistry, 2017, 2017(35), 5225-5230

合成路线：1 步

13146-23-1

_98%

932-88-7

反应条件：

1.1 Reagents: Sodium bicarbonate , Iodine Solvents: Dimethylformamide ; 10 min, rt

参考文献：

Tandem Synthesis of 3-Chloro-4-iodoisoxazoles from 1-Copper(I) Alkynes, Dichloroformaldoxime, and Molecular Iodine

Chen, Wenwen; Zhang, Jianlan; Wang, Bo; Zhao, Zhouxing; Wang, Xinyan; et al, Journal of Organic Chemistry, 2015, 80(4), 2413-2417

合成路线：1 步

13146-23-1

_98%

932-88-7

反应条件：

1.1 Reagents: N-Iodosuccinimide , Benzyl azide Solvents: Dichloromethane ; 10 min, rt

参考文献：

Tandem Reaction of 1-Copper(I) Alkynes for the Synthesis of 1,4,5-Trisubstituted 5-Chloro-1,2,3-triazoles

Wang, Bo; Zhang, Jianlan; Wang, Xinyan; Liu, Nan; Chen, Wenwen; et al, Journal of Organic Chemistry, 2013, 78(20), 10519-10523

合成路线：1 步

536-74-3

_98%

932-88-7

反应条件：

1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran , Hexane ; -78 °C; 30 min, -78 °C
1.2 Reagents: Iodine Solvents: Tetrahydrofuran ; -78 °C

参考文献：

Enantioselective Alkynylation of Aldehydes with 1-Haloalkynes Catalyzed by Tethered Bis(8-quinolinato) Chromium Complex

Usanov, Dmitry L.; Yamamoto, Hisashi, Journal of the American Chemical Society, 2011, 133(5), 1286-1289

合成路线：1 步

637-44-5

_97%

932-88-7

反应条件：

1.1 Reagents: Triethylamine Solvents: Dichloromethane ; 5 min, rt
1.2 Reagents: 1-Iodo-3,5,5-trimethyl-2,4-imidazolidinedione ; 5 min, rt

参考文献：

Process for the preparation of N-iodoamides

, Israel, , ,

合成路线：1 步

536-74-3

_97%

932-88-7

反应条件：

1.1 Reagents: Morpholine , Iodine Solvents: Benzene ; 30 min, rt
1.2 rt; 18 h, 50 °C

参考文献：

Dual Gold-Catalyzed Head-to-Tail Coupling of Iodoalkynes

Mader, Steffen; Molinari, Lise; Rudolph, Matthias; Rominger, Frank; Hashmi, A. Stephen K., Chemistry - A European Journal, 2015, 21(10), 3910-3913

2-碘苯乙炔(932-88-7)上下游

1-苄基-4-苯基-1,2,3-噻唑反式苯基肉桂砜 2-苯基丙烯酸乙酯 Benzene, 1-methyl-4-[(phenylethynyl)sulfonyl]- 4-(2-苯基-1-乙炔)苯甲腈 1-甲基-4-苯基乙炔苯 α-苯基丙烯酸 4,4'-二甲基联苯 1-甲氧基-4-苯基乙炔苯 1,4-联苯基丁二炔

2-碘苯乙炔(932-88-7)相关文献

1. Development of a transition metal-free polymerization route to functional conjugated polydiynes from a haloalkyne-based organic reaction
Yun Zhang,Engui Zhao,Haiqin Deng,Jacky W. Y. Lam,Ben Zhong Tang Polym. Chem. 2016 7 2492
2. Chemoselective and stereospecific iodination of alkynes using sulfonium iodate(i) salt
Dodla S. Rao,Thurpu R. Reddy,Sudhir Kashyap Org. Biomol. Chem. 2018 16 1508
3. Visible-light photoredox synthesis of internal alkynes containing quaternary carbons
Chang Gao,Jingjing Li,Jipan Yu,Haijun Yang,Hua Fu Chem. Commun. 2016 52 7292
4. A novel photochemical cyclisation of o-bisiodoethynylbenzene to substituted naphthalenes
I. D. Cambell,G. Eglinton J. Chem. Soc. C 1968 2120
5. Studies with acetylenes. Part I. Some reactions of grignard reagents with alk-1-ynyl and alk-1-enyl halides
H. K. Black,D. H. S. Horn,B. C. L. Weedon J. Chem. Soc. 1954 1704
6. Interplay between non-covalent interactions in 1D supramolecular polymers based on 1,4-bis(iodoethynyl)benzene
Lucia González,Sara Graus,Blanca Gaspar,Sheila Espasa,Adrián Velázquez-Campoy,Julen Munarriz,José Luis Serrano,Rosa M. Tejedor,Santiago Uriel Phys. Chem. Chem. Phys. 2021 23 3531
7. Infinite and discrete halogen bonded assemblies based upon 1,2-bis(iodoethynyl)benzene
Eric Bosch,Samantha J. Kruse,Ryan H. Groeneman CrystEngComm 2019 21 990
8. Optical waveguides from 4-aryl-4H-1,2,4-triazole-based supramolecular structures
David Cáceres,Cristina Cebrián,Antonio M. Rodríguez,José R. Carrillo,ángel Díaz-Ortiz,Pilar Prieto,Fátima Aparicio,Fátima García,Luis Sánchez Chem. Commun. 2013 49 621
9. The 8 : 1 : 1 ternary hybrid framework in the system [EDT-TTF˙+][1,4-bis(iodoethynyl)benzene][Re6Se8(CN)6]4 ?: dual noncovalent expression of the octahedral halogen-bond hexa-acceptor nanonode
Anne-Lise Barrès,Abdelkrim El-Ghayoury,Leokadiya V. Zorina,Enric Canadell,Pascale Auban-Senzier,Patrick Batail ?: dual noncovalent expression of the octahedral halogen-bond hexa-acceptor nanonode. Anne-Lise Barrès Abdelkrim El-Ghayoury Leokadiya V. Zorina Enric Canadell Pascale Auban-Senzier Patrick Batail Chem. Commun. 2008 2194
10. Lessons from the Synthetic Chemist Nature
Gerrit Jürjens,Andreas Kirschning,David A. Candito Nat. Prod. Rep. 2015 32 723

2-碘苯乙炔(932-88-7)参考资料

Beilstein：

1905735

PubChem CID：

329764387

223758-79-0(2-(2-iodoethynyl)naphthalene) 792913-82-7((8-甲基-1,4-二氧杂螺[4.5]癸烷-8-基)氨基甲酸叔丁酯) 79324-78-0(1-(3-溴-4-(甲基硫代)苯基)乙酮) 78861-31-1(1,4-丁二醇，1-（4-甲基苯基）-) 78930-16-2(4-羟基-4-苯氧基苯甲酮) 78946-25-5(3-溴-4-(溴甲基)苯甲酸甲酯) 79456-27-2(6-氯-3-(三氟甲基)吡啶-2-胺) 795310-80-4(4-(3-甲基-1,2,4-氧杂二唑-5-基)哌啶盐酸盐)

问答

960化工网为您提供2-碘苯乙炔专业化合物百科信息，包括中文名，英文名，分子式，分子量，以及该化合物的CasNo.932-88-7,相关理化性质;并提供了优质生产厂家信息包括厂家名称和联系方式等。 WAP版:932-88-7 国际站:932-88-7

932-88-7 (2-碘苯乙炔,(Iodoethynyl)benzene)

2-碘苯乙炔(932-88-7)名称与标识符

名称

标识符

2-碘苯乙炔(932-88-7)物化性质

实验特性

计算特性

2-碘苯乙炔(932-88-7)安全信息

2-碘苯乙炔(932-88-7)海关数据

中国海关编码：

概述：

申报要素：

Summary：

2-碘苯乙炔(932-88-7)推荐厂家 更多厂家(6)

2-碘苯乙炔(932-88-7)合成路线

2-碘苯乙炔(932-88-7)上下游

2-碘苯乙炔(932-88-7)相关文献

2-碘苯乙炔(932-88-7)参考资料

目录

2-碘苯乙炔(932-88-7)推荐厂家更多厂家(6)